Fe + 2HCl --> FeCl2 + H2
a---------2a------------a
Mg +2 HCl -----> MgCl2 + H2
b------2b----------------------------b
\(\left\{{}\begin{matrix}56a+24b=18,4\\a+b=0,5\end{matrix}\right.\)=>a=0,2 b=0,3
%mFe=0.2.56/18,4=60,87
%mMg=100-60,87=39,13
FeCl2 + 2NaOH--> Fe(OH)2 + 2NaCl
0,2----------0,4
MgCl2 + 2NaOH ------> Mg(OH)2 + 2NaCl
0,3---------0,6
mNaOH=(o,4+0,6).40=40
mdd=40.100/25=160
Đặt :
nFe = x mol
nMg = y mol
mhh= 56x + 24y = 18.4 g (1)
nHCl = 1.2 mol
nH2 = 0.5 mol
Fe + 2HCl --> FeCl2 + H2
x____________x______x
Mg + 2HCl --> MgCl2 + H2
y______________y______y
<=> x + y = 0.5 (2)
Giải (1) và (2) :
x = 0.2
y = 0.3
nHCl dư = 1.2 - 1 = 0.2 mol
NaOH + HCl --> NaCl + H2O
0.2______0.2
FeCl2 + 2NaOH --> Fe(OH)2 + 2NaCl
0.2______0.4
MgCl2 + 2NaOH --> Mg(OH)2 + 2NaCl
0.3_______0.6
\(\sum\) nNaOH = 0.4 + 0.6 + 0.2 = 1 .2 mol
mNaOH = 48 g
mdd NaOH = 48*100/25=192 g