nH2 = \(\dfrac{5,6}{22,4}\)= 0,25 (mol)
mCu = 2 (g)
=> mAl, Fe = 10,3 - 2 = 8,3 (g)
Gọi x, y lần lượt là số mol của Al, Fe
2Al + 6HCl ----> 2AlCl3 + 3H2
x \(\dfrac{3}{2}\)x (mol)
Fe + 2HCl ----> FeCl2 + H2
y y (mol)
Theo đề ra, ta có:
\(\dfrac{3}{2}\)x + y = 0,25
27x + 56y = 8,3
=> x = 0,1
y = 0,1
=> mAl = 0,1.27 = 2,7 (g)
=> %Al = \(\dfrac{2,7.100\%}{10,3}\)= 26,21%
=> %Cu = \(\dfrac{2.100\%}{10,3}\)= 19,42%
=> %Fe = 100 - 26,21 - 19,42 = 54,37%
b,
nCu = \(\dfrac{2}{64}\)= \(\dfrac{1}{32}\) (mol)
2Al + 3Cl2 ----> 2AlCl3
0,1 0,15 (mol)
2Fe + 3Cl2 ----> 2FeCl3
0,1 0,15 (mol)
Cu + Cl2 ----> CuCl2
\(\dfrac{1}{32}\) \(\dfrac{1}{32}\) (mol)
=> nCl2 = 0,15 + 0,15 + \(\dfrac{1}{32}\) = \(\dfrac{53}{160}\) (mol)
=> VCl2 = \(\dfrac{53}{160}\).22,4 = 7,42 (l)