Câu 1 :
\(n_{KMnO4}=\frac{94,8}{158}=0,6\left(mol\right)\)
\(n_{O2\left(spư\right)}=\frac{8,64}{32}=0,27\left(mol\right)\)
\(2KMnO_4\underrightarrow{^{to}}K_2MnO_2+MnO_2+O_2\)
0,6___________________________0,3__(mol)
\(n_{O2}=\frac{1}{2}.0,6=0,3\left(mol\right)\)
\(\Rightarrow n_{O2\left(bị.that.thoat\right)}=0,3-0,27=0,03\left(mol\right)\)
Câu 2 :
\(n_{Fe}=\frac{3,36}{56}=0,06\left(mol\right)\)
\(n_{O2}=\frac{4,8}{32}=0,15\left(mol\right)\)
a,
\(PTHH:3Fe+2O_2\rightarrow Fe_3O_4\)
Theo PT:3____3______________
Theo đề : 0,06____0,15___________
Tỉ lệ:
\(\frac{0,06}{3}=0,02< \frac{0,15}{2}=0,075\)
Sau phản ứng O2 dư , Fe hết
\(n_{O2\left(pư\right)}=\frac{2}{3}n_{Fe}=\frac{2}{3}.0,06=0,04\left(mol\right)\)
\(\Rightarrow n_{O2\left(dư\right)}=0,15-0,04=0,11\left(mol\right)\)
\(\Rightarrow m_{O2\left(dư\right)}=0,11.32=3,52\left(g\right)\)
b, Theo PT:
\(n_{Fe3O4}=\frac{1}{3}n_{Fe}=\frac{1}{3}.0,06=0,02\left(mol\right)\)
\(\Rightarrow m_{Fe3O4}=0,02.232=4,64\left(g\right)\)
1)\(2KMnO4-->K2MnO4+MnO2+O2\)
\(n_{KMnO4}=\frac{94,8}{158}=0,6\left(mol\right)\)
\(n_{O2}=\frac{1}{2}n_{KMnO4}=0,3\left(mol\right)\)
\(m_{O2}=0,3.32=9,6\left(g\right)\)
% oxi bị thất thoát =\(\frac{8,64}{9,6}.100\%=90\%\)
2)\(3Fe+2O2-->Fe3O4\)
a)\(n_{Fe}=\frac{3,36}{56}=0,06\left(mol\right)\)
\(n_{O2}=\frac{4,8}{32}=0,15\left(mol\right)\)
\(n_{Fe}\left(\frac{0,06}{3}\right)< n_{O2}\left(\frac{0,15}{2}\right)=>O2dư\)
\(n_{O2}=\frac{2}{3}n_{Fe}=0,04\left(mol\right)\)
\(n_{O2}dư=0,15-0,04=0,11\left(mol\right)\)
\(m_{O2}dư=0,11.32=3,52\left(g\right)\)
b)\(n_{Fe3O4}=\frac{1}{3}n_{Fe}=0,02\left(mol\right)\)
\(m_{Fe3O4}=0,02.232=4,46\left(g\right)\)