Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ m_{HCl}=200.27,375\%=54,75\left(g\right)\\ n_{HCl}=\dfrac{54,75}{36,5}=1,5\left(mol\right)\)

PTHH:

Zn + 2HCl ---> ZnCl₂ + H₂

a ----> 2a --------> a -----> a

Fe + 2HCl ---> FeCl₂ + H₂

b ---> 2b -------> b ------> b

Hệ pt \(\left\{{}\begin{matrix}65a+56b=43,7\\a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}m_{Zn}=0,5.65=32,5\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)

\(m_{dd}=43,7+200-0,7.2=242,3\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,5.136}{242,3}=28,06\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{242,3}=10,48\%\\C\%_{HCl\left(dư\right)}=\dfrac{\left(1,5-0,5.2-0,2.2\right).36,5}{242,3}=1,51\%\end{matrix}\right.\)

\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ pthh:\left\{{}\begin{matrix}Zn+H_2SO_4->ZnSO_4+H_2\\Fe+H_2SO_4->FeSO_{\text{ 4 }}+H_2\end{matrix}\right.\)
 gọi số mol Zn là x , số mol Fe là y 
=> 65x+56y=43,7
=> a+b=0,7 
=>a=0,5 , b =0,2  
=> \(m_{Zn}=0,5.65=32,5\\ m_{Fe}=43,7-32,5=11,2\left(G\right)\)
 

Trong \(20,4g\) hỗn hợp có: \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow65a+56b+27c=20,4\left(1\right)\)

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)

\(BTe:2n_{Zn}+2n_{Fe}+3n_{Al}=2n_{H_2}\)

\(\Rightarrow2a+2b+3c=2\cdot0,45\left(2\right)\)

Trong \(0,2mol\) hhX có \(\left\{{}\begin{matrix}Zn:ka\left(mol\right)\\Fe:kb\left(mol\right)\\Al:kc\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow ka+kb+kc=0,2\)

\(n_{Cl_2}=\dfrac{6,16}{22,4}=0,275mol\)

\(BTe:2n_{Zn}+3n_{Fe}+3n_{Al}=2n_{Cl_2}\)

\(\Rightarrow2ka+3kb+3kc=2\cdot0,275\)

Xét thương:

 \(\dfrac{ka+kb+kc}{2ka+3kb+3kc}=\dfrac{0,2}{2\cdot0,275}\Rightarrow\dfrac{a+b+c}{2a+3b+3c}=\dfrac{4}{11}\)

\(\Rightarrow3a-b-c=0\left(3\right)\)

Từ (1), (2), (3)\(\Rightarrow\left\{{}\begin{matrix}a=0,1mol\\b=0,2mol\\c=0,1mol\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Zn}=6,5g\\m_{Fe}=11,2g\\m_{Al}=2,7g\end{matrix}\right.\)

a/ Fe + 2HCl \(\rightarrow\) FeCl₂ + H₂

n_H2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PTHH: n_H2 = n_Fe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)

\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)

\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)

\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)

b/ Theo PTHH ta có: n_HCl = 2n_Fe = 2.0,15 = 0,3 (mol)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)

c/ m_HCl = 36,5 . 0,3 = 10,95(g)

\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)

b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)

c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)

nè bạn...... cái khúc cuối là y=0,2 mol đó, b hc chuyên Hóa à?

$n_{H_2}=\dfrac{15,68}{22,4}=0,7mol$

$PTHH :$

$Zn+2HCl\to ZnCl_2+H_2$

$Fe+2HCl\to FeCl_2+H_2$

a.Gọi $n_{Zn}=a;n_{Fe}=b(a,b>0)$

$\text{Ta có :}$

$m_{hh}=65a+56b=43,7g$

$n_{H_2}=a+b=0,7mol$

$\text{Ta có hpt :}$

\(\left\{{}\begin{matrix}65a+56b=43,7\\a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,2\end{matrix}\right.\)

\(\Rightarrow\) $m_{Zn}=0,5.65=32,5g$

$m_{Fe}=43,7-32,5=11,2g$

$b.n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2mol$

$Fe_3O_4+4H_2\overset{t^o}\to 3Fe+4H_2O$

$\text{Theo pt : 1 mol 4 mol}$

$\text{Theo đbài : 0,2 mol 0,7 mol}$

Tỷ lệ : $\dfrac{0,2}{1}>\dfrac{0,7}{4}$

$\text{=>Sau pư Fe3O4 dư}$

$\text{Theo pt :}$

$n_{Fe}=3/4.n_{H_2}=3/4.0,7=0,525mol

$=>m_{Fe}=0,525.56=29,4g$

a, Ta có: 65n_Zn + 27n_Al = 11,9 (1)

PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=\dfrac{9,916}{24,79}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,1\left(mol\right)\\n_{Al}=0,2\left(mol\right)\end{matrix}\right.\)

⇒ m_Zn = 0,1.65 = 6,5 (g)

m_Al = 0,2.27 = 5,4 (g)

b, Theo PT: n_ZnCl2 = n_Zn = 0,1 (mol)

n_AlCl3 = n_Al = 0,2 (mol)

⇒ m _muối = 0,1.136 + 0,2.133,5 = 40,3 (g)

c, Theo PT: n_HCl = 2n_H2 = 0,8 (mol)

\(\Rightarrow m_{ddHCl}=\dfrac{0,8.36,5}{10\%}=292\left(g\right)\)