Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ m_{HCl}=200.27,375\%=54,75\left(g\right)\\ n_{HCl}=\dfrac{54,75}{36,5}=1,5\left(mol\right)\)
PTHH:
Zn + 2HCl ---> ZnCl2 + H2
a ----> 2a --------> a -----> a
Fe + 2HCl ---> FeCl2 + H2
b ---> 2b -------> b ------> b
Hệ pt \(\left\{{}\begin{matrix}65a+56b=43,7\\a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Zn}=0,5.65=32,5\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
\(m_{dd}=43,7+200-0,7.2=242,3\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,5.136}{242,3}=28,06\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{242,3}=10,48\%\\C\%_{HCl\left(dư\right)}=\dfrac{\left(1,5-0,5.2-0,2.2\right).36,5}{242,3}=1,51\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\
pthh:\left\{{}\begin{matrix}Zn+H_2SO_4->ZnSO_4+H_2\\Fe+H_2SO_4->FeSO_{\text{ 4 }}+H_2\end{matrix}\right.\)
gọi số mol Zn là x , số mol Fe là y
=> 65x+56y=43,7
=> a+b=0,7
=>a=0,5 , b =0,2
=> \(m_{Zn}=0,5.65=32,5\\ m_{Fe}=43,7-32,5=11,2\left(G\right)\)
