a, - MgO không bị khử bởi H₂.

PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{CuO}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{CuO}=0,1.80=8\left(g\right)\)

\(\Rightarrow m_{MgO}=16-8=8\left(g\right)\)

b, Ta có: \(\%m_{CuO}=\%m_{MgO}=\dfrac{8}{16}.100=50\%\)

c, Theo PT: \(n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Cu}=0,1.64=6,4\left(g\right)\)

Gọi \(\left\{{}\begin{matrix}n_{CuO}=x\\n_{MgO}=y\end{matrix}\right.\)

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

   x                           x                   ( mol )

\(MgO+2HCl\rightarrow MgCl_2+H_2O\)

 y                            y                  ( mol )

Ta có:

\(\left\{{}\begin{matrix}80x+40y=16\\135x+95y=32,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\Rightarrow m_{CuO}=0,1.80=8g\)

\(\Rightarrow m_{MgO}=0,2.40=8g\)

\(\%m_{CuO}=\dfrac{8}{16}.100=50\%\)

\(\%m_{MgO}=\dfrac{8}{16}.100=50\%\)

\(m_{CuCl_2}=0,1.135=13,5g\)

\(m_{MgCl_2}=0,2.95=19g\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

a.

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

b.

\(n_{Mg}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right),m_{CuO}=12-2,4=9,6\left(g\right)\)

c. 

\(m_{muối}=m_{CuCl_2}+m_{MgCl_2}=0,12.135+95.0,1=25,7\left(g\right)\)

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)  (1)

             \(MgO+2HCl\rightarrow MgCl_2+H_2O\)  (2)

a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)

\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)

b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)

\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)

c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)

\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)

Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)

\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)

a) Gọi $n_{Al} = a(mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 33,4(1)$

$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH : $n_{H_2} = 1,5a + b = \dfrac{17,92}{22,4} = 0,8(2)$

Từ (1)(2) suy ra : a = 0,2 ; b = 0,5

$\%m_{Al} = \dfrac{0,2.27}{33,4}.100\% = 16,17\%$
$\%m_{Fe} = 100\% - 16,17\% = 83,83\%$

b) $n_{HCl} = 2n_{H_2} = 1,6(mol)$

c) $m_{muối} = m_{hh} + m_{HCl} - m_{H_2} = 33,4 + 1,6.36,5 - 0,8.2 = 90,2(gam)$

n_H2 \(\approx\)0,2 (mol)

Mg + 2HCl \(\rightarrow\) MgCl₂ + H₂ (1)

0,2 <------------ 0,2 <----- 0,2 (mol)

MgO + 2HCl \(\rightarrow\) MgCl₂ + H₂O (2)

b) %^mMg = \(\frac{0,2.24}{8,8}\) . 100% =54,55%

%^mMgO = 45,45%

c) m_MgO = 8,8 - 0,2 . 24 = 4(g)

=> n_MgO=0,1 (mol)

Theo pt(2) n_MgCl2 = n_Mg = 0,1 (mol)

=> \(\Sigma n_{MgCl_2}\) = 0,2 + 0,1 = 0,3 (mol)

m_muối = 0,3 . 95 = 28,5 (g)