Cho hỗn hợp qua dung dịch brom dư

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Khí thoát ra là \(CH_4\)

\(CH_4+2O_2\rightarrow^{t^o}CO_2+2H_2O\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

Ta có:

\(n_{CaCO_3}=\frac{40}{100}=0,4mol=n_{CO_2}=n_{CH_4}\)

\(\rightarrow V_{CH_4}=0,4.22,4=8,96l\)

\(\rightarrow\%V_{CH_4}=\frac{8,96}{13,56}=66\%\rightarrow\%V_{C_2H_4}=34\%\)

a,\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:      x                                 x    

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:      y                                 y

Ta có: \(\left\{{}\begin{matrix}65x+56y=30,7\\x+y=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\%m_{Zn}=\dfrac{0,3.65.100\%}{30,7}=63,52\%;\%m_{Fe}=100\%-63,52\%=36,48\%\)

b,

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:     0,3     0,6                             

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:     0,2     0,4

n_HCl = 0,6+0,4 = 1 (mol)

\(V_{ddHCl}=\dfrac{1}{2}=0,5\left(l\right)=500\left(ml\right)\)

a, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)

Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,2\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,2.22,4}{6,72}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)

b, Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=0,7\left(mol\right)\)

\(\Rightarrow V_{O_2}=0,7.22,4=15,68\left(l\right)\)

2CH3COOH+CaCO3-to>(CH3COO)2Ca+H2O+CO2

0,4-----------------0,2----------------------------------------0,2

2CH3COOH+CaO->(CH3COO)2Ca+H2O

0,1----------------0,05

n CO2=0,2 mol

=>%m CaCO3=\(\dfrac{0,2.100}{22,8}100=87,72\%\)

=>%m CaO=12,28%

=>n CaO=0,05 mol

=>VCH3COOH=\(\dfrac{0,5}{2}=0,25l\)

a)

\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: CaCO₃ + 2CH₃COOH --> (CH₃COO)₂Ca + CO₂ + H₂O

                0,2<---------0,4<------------------------------0,2

=> \(m_{CaCO_3}=0,2.100=20\left(g\right)\)

=> \(\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{20}{22,8}=87,72\%\\\%m_{CaO}=100\%-87,72\%=12,28\%\end{matrix}\right.\)

b)

\(n_{CaO}=\dfrac{22,8-20}{56}=0,05\left(mol\right)\)

PTHH: CaO + 2CH₃COOH --> (CH₃COO)₂Ca + H₂O

            0,05---->0,1

=> \(V_{dd.CH_3COOH}=\dfrac{0,1+0,4}{2}=0,25\left(l\right)\)

c) \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{a}{60}\left(mol\right)\\n_{C_2H_5OH}=\dfrac{1,5a}{46}\left(mol\right)\\n_{CH_3COOC_2H_5}=\dfrac{1,2a}{88}\left(mol\right)\end{matrix}\right.\)

PTHH: CH₃COOH + C₂H₅OH --H₂SO_4(đ),t^o--> CH₃COOC₂H₅ + H₂O

Xét tỉ lệ: \(\dfrac{\dfrac{a}{60}}{1}< \dfrac{\dfrac{1,5a}{46}}{1}\) => HIệu suất tính theo CH₃COOH

\(n_{CH_3COOH\left(pư\right)}=\dfrac{1,2a}{88}\left(mol\right)\)

=> \(H=\dfrac{\dfrac{1,2a}{88}}{\dfrac{a}{60}}.100\%=81,82\%\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ FeO+H_2SO_4\rightarrow FeSO_4+H_2O\\ n_{Zn}=n_{H_2}=0,2mol\\ \%m_{Zn}=\dfrac{0,2.65}{20}\cdot100\%=65\%\\ \%m_{Fe}=100\%-65\%=35\%\)

Gọi \(\left\{{}\begin{matrix}n_{H_2}=a\left(mol\right)\\n_{CO}=b\left(mol\right)\end{matrix}\right.\)⇒ 2a + 28b = 6,8(1)

\(2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ 2CO + O_2 \xrightarrow{t^o} 2CO_2\)

Theo PTHH :

\(n_{O_2} = 0,5a + 0,5b = \dfrac{8,96}{22,4} = 0,4(2)\)

Từ (1)(2) suy ra: a = 0,6 ; b = 0,2

Vậy :

\(\%m_{H_2} = \dfrac{0,6.2}{6,8}.100\% = 17,65\%\\ \%m_{CO} = 100\% - 17,65\% = 82,35\%\)

Đáp án B

Khi cho CO và CO₂ qua than nóng đỏ dó phản ứng:

CO₂ + C → 2CO ⇒ Số mol hỗn hợp tăng lên chính là số mol CO₂ đã tham gia phản ứng.

⇒ n_{CO2 đã pứ} = (7 – 5,6) ÷ 22,4 = 0,0625 mol.

Số mol CO₂ còn lại = n_CaCO3 = 6,25 ÷ 100 = 0,0625 mol.

⇒ n_{CO2 ban đầu} = 0,0625 + 0,0625 = 0,125 mol.

Tóm lại n_CO2/X = 0,125 mol và n_CO2/Y = 0,0625