nP = 2,48/31 = 0,08 (mol)

PTHH: 4P + 5O2 -> (t°) 2P2O5

Mol: 0,08 ---> 0,1 ---> 0,04

mP2O5 = 0,04 . 142 = 5,68 (g)

b) nO2 = 4/32 = 0,125 (mol)

So sánh: 0,125 > 0,1 => O2 dư

nO2 (dư) = 0,125 - 0,1 = 0,025 (mol)

mO2 (dư) = 0,025 . 32 = 0,8 (g)

\(a,PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\\ m_{Al_2O_3}=n.M=0,2.102=20,4\left(g\right)\)

\(b,n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ Lập.tỉ.lệ:\dfrac{n_{Al}}{4}>\dfrac{n_{O_2}}{3}\Rightarrow Al.dư\\ Theo.PTHH:n_{Al\left(pư\right)}=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,2\left(mol\right)\\ n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(pư\right)}=0,4-0,2=0,2\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{Al_2O_3}=n.M=0,1=102=10,2\left(g\right)\)

\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\) 
          0,4                0,2 
\(m_{P_2O_5}=142.0,2=28,4g\) 
\(n_{O_2}=\dfrac{17}{32}=0,53\left(mol\right)\)  
\(pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,4}{4}< \dfrac{0,53}{5}\) 
=> O2 dư 
\(n_{O_2\left(p\text{ư}\right)}=\dfrac{5}{4}n_P=0,5\left(mol\right)\\ m_{O_2\left(d\right)}=\left(0,53-0,5\right).32=0,96g\)

`4P + 5O_2` $\xrightarrow[]{t^o}$ `2P_2 O_5`

`0,4`    `0,5`              `0,2`              `(mol)`

`n_P = [ 12,4 ] / 31 = 0,4 (mol)`

`a) m_[P_2 O_5] = 0,2 . 142 = 28,4 (g)`

`b) n_[O_2] = 17 / 32 = 0,53125 (mol)`

Ta có: `[ 0,4 ] / 4 < [ 0,53125 ] / 5`

     `->O_2` dư

`=> m_[O_2 (dư)] = ( 0,53125 - 0,5 ) . 32 = 1(g)`

\(n_{Na}=\dfrac{3,45}{23}=0,15mol\)

\(n_{O_2}=\dfrac{0,56}{22,4}=0,025mol\)

\(4Na+O_2\underrightarrow{t^o}2Na_2O\)

0,15     0,025   0

0,1       0,025   0,05

0,05      0         0,05

Sau phản ứng Na dư và dư \(0,05\cdot23=1,15g\)

nNa = 3,45/23 = 0,15 (mol)

nO2 = 0,56/22,4 = 0,025 (mol)

PTHH: 4Na + O2 -> (t°) 2Na2O

LTL: 0,15/4 > 0,025 => Na dư

nNa (p/ư) = 0,025 . 4 = 0,1 (mol)

mNa (dư) = (0,15 - 0,1) . 23 = 1,15 (g)

nNa=3,45:23=0,15(mol)
nO2 = 0,56: 22,4 =0,025(mol) 
PTHH : 4Na+O2-t--> 2Na2O 
LTL : 
 0,15/4   >   0,025/1
=> Na dư 
ta có nNa(phản ứng ) = nO2 = 0,025(mol) 
 =>nNa dư = nNa(ban đầu) - nNa(pư) = 0,15-0,025=0,125(mol) 
mNa(dư) = 0,125.23=2,875(g)

\(n_{O_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(n_{N_2O_5}=\dfrac{10.8}{108}=0.1\left(mol\right)\)

\(2N_2+5O_2\underrightarrow{t^0}2N_2O_5\)

\(.......0.25.....0.1\)

\(m_{O_2\left(dư\right)}=\left(0.3-0.25\right)\cdot32=1.6\left(g\right)\)

nP=\(\dfrac{62}{31}\)=0,2(mol)

nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)

PTHH:4P+5O2to→2P2O5

tpứ:    0,2     0,35     

pứ:     0,2     0,25     0,1

spứ:     0     0,1         0,1

a)chất còn dư là oxi

mO2dư=0,1.32=3,2(g)

b)mP2O5=n.M=0,1.142=14,2(g)

\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)

a) n\(_P\) = \(\dfrac{6,2}{31}\) = 0,2(mol); n\(_{O_2}\) = \(\dfrac{7,84}{22,4}\) = 0,35(mol).

Theo phương trình hóa học:

\(4P+5O_2\) \(\underrightarrow{t^o}\) \(2P_2O_5\)

4        5          2 (mol)

0,2 \(\rightarrow\)0,25 \(\rightarrow\) 0,1(mol)

Tỉ lệ số mol: \(\dfrac{0,2}{4}< \dfrac{0,35}{5}\) \(\Rightarrow\) \(O_2\) phản ứng dư, P phản ứng hết.

\(n_{O_2}\)dư = 0,35 - \(\dfrac{0,2.5}{4}\) = 0,1(mol) \(\Rightarrow\) \(m_{O_2}\)dư = 0,1.32 = 3,2g

b) \(n_{P_2O_5}\) = 0,1.142 = 14,2g

a. \(n_P=\dfrac{12.4}{31}=0,4\left(mol\right)\)

\(n_{O_2}=\dfrac{67.2}{22,4}=3\left(mol\right)\)

Ta thấy : 0,4 < 3 => P đủ , O₂ dư

PTHH : 4P + 5O₂ -----t^o-----> 2P₂O₅

            0,4     0,5                      0,2

b. \(m_{P_2O_5}=0,2.142=28,4\left(g\right)\)