MgCl2+2AgNO3->Mg(NO3)2+2AgCl

0,04-----0,08-----------0,04----------0,08

n MgCl2=0,1 mol

n AgNO3=0,08 mol

=>Mgcl2 dư

=>m AgCl=0,08.143,5=11,48g

=>CMMg(NO)2=\(\dfrac{0,04}{0,2}\)=0,2M

=>CMMgcl2 dư=\(\dfrac{0,06}{0,2}\)=0,3M

\(n_{MgCl_2}=0,1\cdot1=0,1mol\)

\(n_{AgNO_3}=0,1\cdot0,8=0,08mol\)

\(MgCl_2+2AgNO_3\rightarrow2AgCl\downarrow+Mg\left(NO_3\right)_2\)

0,1            0,08                 0              0

0,04          0,08                 0,08         0,04

0,06          0                      0,08         0,04

\(m_{\downarrow}=0,08\cdot143,5=11,48g\)

\(C_{M_{Mg\left(NO_3\right)_2}}=\dfrac{n_{Mg\left(NO_3\right)_2}}{V_X}=\dfrac{0,04}{0,2}=0,2M\)

\(n_{MgCl_2}=0,1.1=0,1\left(mol\right)\\ n_{AgNO_3}=0,1.0,8=0,08\left(mol\right)\)

PTHH: MgCl₂ + 2AgNO₃ ---. 2AgCl + Mg(NO₃)₂

LTL: \(0,1>\dfrac{0,08}{2}\rightarrow\) MgCl₂ dư

Theo pthh: \(\left\{{}\begin{matrix}n_{MgCl_2\left(pư\right)}=n_{Mg\left(NO_3\right)_2}=\dfrac{0,08}{2}=0,04\left(mol\right)\\n_{AgCl}=0,08\left(mol\right)\end{matrix}\right.\)

\(\rightarrow C_M_{MgCl_2\left(dư\right)}==\dfrac{0,1-0,04}{0,2}=0,3M\\ C_{MMg\left(NO_3\right)_2}=\dfrac{0,04}{0,2}=0,2M\)

\(m_{AgCl}=143,5.0,08=11,48\left(g\right)\)

a, \(n_{HCl}=0,2.0,1=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)

\(n_{H_2SO_4}=0,2.0,15=0,03\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,06\left(mol\right)\)

\(\Rightarrow\Sigma n_{H^+}=0,02+0,06=0,08\left(mol\right)\)

\(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)=n_{Ba^{2+}}\) 

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

0,03___0,03 (mol) ⇒ n_H⁺ dư = 0,05 (mol)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)

0,015___0,015______0,015 (mol) ⇒ n_SO4^2- dư = 0,015 (mol)

⇒ m = m_BaSO4 = 0,015.233 = 3,495 (g)

\(\left[Cl^-\right]=\dfrac{0,02}{0,2+0,3}=0,04\left(M\right)\)

\(\left[H^+\right]=\dfrac{0,05}{0,2+0,3}=0,1\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0,015}{0,2+0,3}=0,03\left(M\right)\)

b, pH = -log[H⁺] = 1

\(n_{NaOH}=1.0,4=0,4(mol);n_{FeCl_3}=1.0,1=0,1(mol)\\ a,PTHH:3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \text {Vì }\dfrac{n_{NaOH}}{3}>\dfrac{n_{FeCl_3}}{1} \text {nên }NaOH\text { dư}\\ \Rightarrow n_{Fe(OH)_3}=0,1(mol)\\ \Rightarrow m_{Fe(OH)_3}=107.0,1=10,7(g)\\ b,n_{NaCl}=3n_{FeCl_3}=0,3(mol)\\ \Rightarrow C_{M_{NaCl}}=\dfrac{0,3}{0,4+0,1}=0,6M\)

Đáp án cần chọn là: B

Gọi: \(\left\{{}\begin{matrix}n_{FeCl_3}=x\left(mol\right)\\n_{MgCl_2}=y\left(mol\right)\end{matrix}\right.\)

PT: \(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_{3\downarrow}+3KCl\)

______x_________3x_________x (mol)

\(MgCl_2+2KOH\rightarrow Mg\left(OH\right)_{2\downarrow}+2KCl\)

____y_________2y_________y (mol)

Ta có: \(n_{KOH}=0,2.2,5=0,5\left(mol\right)\)

⇒ 3x + 2y = 0,5 (1)

m _{kết tủa} = 16,5 ⇒ 107x + 58y = 16,5 (2)

Từ (1) và (2) ⇒ x = y = 0,1 (mol)

\(\Rightarrow C_{M_{FeCl_3}}=C_{M_{MgCl_2}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

\(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_3\downarrow+3KCl\\ MgCl_2+2KOH\rightarrow Mg\left(OH\right)_2\downarrow+2KCl\)

\(n_{KOH}=0,2\cdot2,5=0,5\left(mol\right)\)

Đặt n_FeCl₃ trong 500ml X là a mol, n_MgCl₂ trong 500ml X là b mol

\(\Rightarrow\left\{{}\begin{matrix}3a+2b=0,5\\107a+58b=16,5\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow C_MFeCl_3=\dfrac{0,1}{0,5}=0,2\left(M\right)\\ C_MMgCl_2=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

Đáp án A

Đáp án D