PTHH : 2NaOH + H₂SO₄ ---> Na₂SO₄+2H₂O

0.06 0. 03 0.03 0.03 (mol)

n_{H2SO4=0.3 x 0.1 =0.03 mol}

Theo PTHH n_NaOH=0.06 mol

m_NaOH =0.06 x 40=2.4g

VNaOH = 2.4 x 1.2 = 2.88 g

Vậy cần 2.88 g dd NaOH 0.1 M để hòa tan 300 ml dd H₂SO₄

- Trong 300 ml dung dịch X:

\(\text{nHCl = 0,3.0,3 = 0,09 mol}\)

\(\text{nH2SO4 = 0,2.0,3 = 0,06 mol}\)

\(\text{nH3PO4 = 0,1.0,3 = 0,03 mol}\)

-Trong V ml dung dịch Y chứa:

\(\text{nNaOH = 0,1.0,001V = 0,0001V (mol)}\)

\(\text{nBa(OH)2 = 0,2.0,001V = 0,0002V (mol)}\)

Phản ứng trung hòa tổng quát: b HaX + a M(OH)b → MaXb + ab H2O

Từ pư tổng quát ta thấy: nH = nOH

\(\text{+ BTNT "H": nH = nHCl + 2nH2SO4 + 3nH3PO4}\)

\(\text{+ BTNT "OH": nOH = nNaOH + 2nBa(OH)2}\)

=> nHCl + 2nH2SO4 + 3nH3PO4 = nNaOH + 2nBa(OH)2

=> 0,09 + 2.0,06 + 3.0,03 = 0,0001V + 2.0,0002V

=> V = 600 ml

\(\begin{matrix}n_{HCl}=0,09\\n_{H_2SO_4}=0,06\\n_{H_3PO_4}=0,03\end{matrix}\)

\(\sum n_{H^+}=0,09+0,06.2+0,03.3=0,3\)

\(\begin{matrix}n_{NaOH}=0,1V\\n_{Ba\left(OH\right)_2}=0,2V\end{matrix}\)

\(\sum n_{OH^-}=0,1V+0,2V.2=0,5V\)

\(H^++OH^-\rightarrow H_2O\)

\(\Leftrightarrow0,5V=0,3\Rightarrow V=600ml\)

\(n_{Ba\left(OH\right)_2}=0,3.0,1=0,03\left(mol\right)\\ n_{HCl}=0,2.0,15=0,03\left(mol\right)\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ Vì:\dfrac{n_{Ba\left(OH\right)_2\left(đề\right)}}{n_{Ba\left(OH\right)_2\left(PTHH\right)}}=\dfrac{0,03}{1}>\dfrac{n_{HCl\left(đề\right)}}{n_{HCl\left(PTHH\right)}}=\dfrac{0,03}{2}\\ \Rightarrow Ba\left(OH\right)_2dư\\ n_{Ba\left(OH\right)_2\left(p.ứ\right)}=\dfrac{n_{HCl}}{2}=\dfrac{0,03}{2}=0,015\\ n_{Ba\left(OH\right)_2\left(dư\right)}=0,03-0,015=0,015\left(mol\right)\\ \left[OH^-\right]=2.\left[Ba\left(OH\right)_2\left(dư\right)\right]=\dfrac{0,015}{0,3+0,2}=0,03\left(M\right)\\ \Rightarrow pH=14+log\left[OH^-\right]=14+log\left[0,03\right]\approx12,477\)