ta có :

nBr2=\(\dfrac{16}{160}=0,1mol\)

C2H4+Br2->C2H4Br2

0,1------0,1

=>VC2H4=0,1.22,4=2,24l

=>VCH4=3,36l->n CH4=0,15 mol

->%VC2H4=\(\dfrac{2,24}{5,6}.100\)=40%

=>%VCH4=60%

c)

CH4+2O2-to>CO2+2H2O

0,15---------------0,15

C2H4+3O2--to>2CO2+2H2O

0,1--------------------0,2
=>m CaCO3=0,35.100=35g

Đáp án B

Crackinh 0,2 mol C₄H₁₀ → hhX gồm 5 hiđrocacbon.

hhX qua bình Brom dư → m_{bình tăng} = 8,4 gam

• Khí bay ra khỏi dung dịch Brom là hiđrocacbon no CT  

→ n_Y = 0,2 mol, m_hhY = 0,2 x 58 - 8,4 = 3,2 gam.

→ M = 16 → n = 1

 → V_O2 = 22,4 x 0,4 = 8,96 lít

a) PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Ta có: \(n_{C_2H_4}=\dfrac{5,6}{28}=0,2\left(mol\right)=n_{C_2H_4Br_2}\) \(\Rightarrow m_{C_2H_4Br_2}=0,2\cdot188=37,6\left(g\right)\)

b) Ta có: \(n_{CH_4}=\dfrac{11,2}{22,4}-0,2=0,3\left(mol\right)\)

Bảo toàn nguyên tố: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=0,7\left(mol\right)\)

\(\Rightarrow V_{CO_2}=0,7\cdot22,4=15,68\left(l\right)\)

m(bình tăng) = mC2H2 = 1,04(g) => nC2H2 = 0,04(mol)

nO2 = \(\dfrac{3,808}{22,4}=0,17\left(mol\right)\)

PTHH :

C2H2 + 2Br2 - > C2H2Br4

C2H2 + 5/2O2 -^t0-> 2CO2 + H2O

0,04mol...0,1mol

=> nO2(còn lại) = 0,17 - 0,1 = 0,07(mol)

C2H6 + 3,5O2-^t0-> 2CO2 + 3H2O

0,02mol....0,07mol

=> VC2H6 = 0,02.22,4 =0,448(l)(l)

VC2H2 = 0,04.22,4 = 0,896(l)

a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

Giả sử: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow x+y=\dfrac{1,344}{22,4}=0,06\left(1\right)\)

Ta có: \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y\left(mol\right)\)

⇒ x + 2y = 0,1 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,04\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,02}{0,06}.100\%\approx33,33\%\\\%\text{ }V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)

b, Ta có: 1/2 hỗn hợp khí gồm: 0,01 mol C₂H₄ và 0,02 mol C₂H₂.

PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Theo PT: \(n_{CO_2}=2n_{C_2H_4}+2n_{C_2H_2}=0,06\left(mol\right)\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)

Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,06\left(mol\right)\)

\(\Rightarrow m_{cr}=m_{CaCO_3}=0,06.100=6\left(g\right)\)

Bạn tham khảo nhé!