Á dơ quá mình làm luôn vậy :v Tại đọc nhầm đề tưởng khí cho vào:3

Ta có: \(n_{H_2}=0,6a\left(mol\right);n_{CO_2}=0,4a\left(mol\right)\)

PTHH: \(2Al+6HCl-->2AlCl_3+3H_2\\ FeCO_3+2HCl-->FeCl_2+CO_2+H_2O\)

Suy ra \(27.0,4a+0,4a.116=28,6\Rightarrow a=0,5\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{FeCO_3}=0,2\left(mol\right)\end{matrix}\right.\)

PTHH: \(3KOH+AlCl_3-->Al\left(OH\right)_3+3KCl\\ 2KOH+FeCl_2-->Fe\left(OH\right)_2+2KCl\\ Al\left(OH\right)_3+KOH-->KAlO_2+2H_2O\)

Suy ra \(n_{KOH}>0,6+0,4+0,2=1,2\)

Do đó \(V>0,6\left(l\right)\)

Mình cũng mạn phép tặng GP cho bạn nào giải ra trường hợp có 3 chất tan

Hmm , 3 chất tan : KCl , KAlO2 , chẳng lẽ có HCl dư :<

\(a,Fe+2HCl\rightarrow FeCl_2+H_2\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\Rightarrow n_{Fe}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Fe}=\dfrac{0,1.56}{13,6}.100\%\approx41,176\%\\ \Rightarrow\%m_{CuO}\approx58,824\%\\ b,n_{CuO}=\dfrac{13,6-0,1.56}{80}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.\left(n_{Fe}+n_{CuO}\right)=2.\left(0,1+0,1\right)=0,4\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)

Câu 1:

Gọi : nMg=a(mol); nMgO=b(mol) (a,b>0)

a) PTHH: Mg + 2 HCl -> MgCl2 + H2

a________2a_______a______a(mol)

MgO +2 HCl -> MgCl2 + H2O

b_____2b_______b___b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24a+40b=8,8\\22,4a=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)

=> mMg=0,2.24=4,8(g)

=>%mMg= (4,8/8,8).100=54,545%

=> %mMgO= 45,455%

b) m(muối)=mMg2+ + mCl- = 0,3. 24 + 0,6.35,5=28,5(g)

c) V=VddHCl=(2a+2b)/2=0,3(l)=300(ml)

Câu 2:

Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{HCl}=0,4\cdot2=0,8\left(mol\right)\end{matrix}\right.\)

PTHH: \(Ca+2HCl\rightarrow CaCl_2+H_2\uparrow\)

               0,2____0,4_____0,2____0,2   (mol)

           \(CaO+2HCl\rightarrow CaCl_2+H_2O\)

                0,2____0,4______0,2____0,2  (mol)

Ta có: \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{0,2\cdot40}{0,2\cdot40+0,2\cdot56}\cdot100\%\approx41,67\%\\\%m_{CaO}=58,33\%\\m_{CaCl_2}=\left(0,2+0,2\right)\cdot111=44,4\left(g\right)\end{matrix}\right.\)

a) Sửa đề: dd H₂SO₄ 9,8%

Ta có: \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\) \(\Rightarrow m_{H_2}=0,35\cdot2=0,7\left(g\right)\)

Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{H_2}=0,35\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,35\cdot98}{9,8\%}=350\left(g\right)\)

\(\Rightarrow m_{dd}=m_{KL}+m_{H_2SO_4}-m_{H_2}=361,6\left(g\right)\)

b) Tương tự câu a

Ta có: n_N2 = 0,22 (mol)

⇒ n_NO3^- = 10n_N2 = 2,2 (mol)

⇒ m _muối = m_X + m_NO3^- = 31 + 2,2.62 = 167,4 (g)

n_HNO3 = 12n_N2 = 2,64 (mol)

\(\Rightarrow V_{HNO_3}=\dfrac{2,64}{2}=1,32\left(l\right)=1320\left(ml\right)\)

`MgCO_3+2HCl->MgCl_2+CO_2+H_2O`

`Mg+2HCl->MgCl_2+H_2`

`FeCO_3+2HCl->FeCl_2+CO_2+H_2O`

Đặt \(\hept{\begin{cases}x\left(mol\right)=n_{H_2}\\y\left(mol\right)=n_{CO_2}\end{cases}}\)

\(\rightarrow2x+44y=4,8\left(1\right)\)

Có \(\overline{M}_B=8.M_{H_2}=16\)

\(\rightarrow n_B=x+y=0,2mol\) và \(y=0,1mol\)

Theo phương trình \(n_{H_2O}=n_{CO_2}=0,1mol\)

BT H \(\text{∑}n_{HCl}=2n_{H_2O}+2n_{H_2}=0,6mol\)

BT khối lượng \(m_A+m_{HCl}=m_{\text{muối}}+m_{CO_2}+m_{H_2O}+m_{H_2}\)

\(\rightarrow m+0,6.36,5=4,8+0,1.18+40,9\)

\(\rightarrow m=25,6g\)

a)
nH2SO4 = 0.5a (mol)
nKOH = 0.4 (mol)
nAl(OH)3 = 0.005 (mol)

Trường hợp 1: H2SO4 dư

H2SO4 + 2KOH -----> K2SO4 + 2H2O
_0.2_____0.4_
nH2SO4dư = 0.5a - 0.2 (mol) => 1/2nH2SO4dư = 0.25a - 0.1 (mol)

2Al(OH)3 + 3H2SO4 -----> Al2(SO4)3 + 6H2O
_0.005____0.0075_
=> 0.25a - 0.1 = 0.0075 => a = 0.43

Trường hợp 2: KOH dư

H2SO4 + 2KOH -----> K2SO4 + 2H2O
_0.5a_____a_
nKOHdư = 0.4 - a (mol) => 1/2nKOHdư = 0.2 - 0.5a (mol)

Al(OH)3 + KOH -----> KAlO2 + 2H2O
_0.005__0.005_
=> 0.2 - 0.5a = 0.005 => a = 0.39

b)

Vì ddA td với Fe3O4 và FeCO3 => ddA có chứa H2SO4 dư, chọn TH1: a = 0.43
=> nH2SO4 trong 100ml ddA = 0.1x0.43 = 0.043 (mol)

Fe3O4 + 4H2SO4 -----> FeSO4 + Fe2(SO4)3 + 4H2O
__x_______4x_
FeCO3 + H2SO4 -----> FeSO4 + H2O + CO2
__y_______y_

mhhB = 2.668 (g) => 232x + 116y = 2.668
nH2SO4 = 0.043 (mol) => 4x + y = 0.043

=> x = 0.01; y = 0.003

mFe3O4 = 2.32 (g)
mFeCO3 = 0.348 (g)