a.\(Fe+S\rightarrow\left(t^o\right)FeS\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(FeS+2HCl\rightarrow FeCl_2+H_2S\)

b.\(n_{hhk}=\dfrac{4,48}{22,4}=0,2mol\)

\(Fe+S\rightarrow\left(t^o\right)FeS\)

Ta thu được hh khí --> S hết, Fe dư

Gọi \(\left\{{}\begin{matrix}n_{Fe}=x\\n_S=y\end{matrix}\right.\)

\(\rightarrow n_{FeS}=n_{Fe}=n_S\rightarrow n_{Fe\left(dư\right)}=x-y\) ( mol )

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(x-y\)                            \(x-y\)        ( mol )

\(FeS+2HCl\rightarrow FeCl_2+H_2S\)

  y                                          y       ( mol )

Ta có: \(\left(x-y\right)+y=0,2\)

           \(\Leftrightarrow x=0,2\)

Ta có:\(56x+32y=14,4\)

        \(\Leftrightarrow56.0,2+32y=14,4\)

        \(\Leftrightarrow y=0,1\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2.56}{14,4}.100=77,77\%\\\%m_S=100\%-77,77\%=22,23\%\end{matrix}\right.\)

\(a)2Na+2HCl\xrightarrow[]{}2NaCl+H_2\\ 2K+2HCl\xrightarrow[]{}2KCl+H_2 \\ b)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ n_{Na}=a,n_K=b\\ \Rightarrow\left\{{}\begin{matrix}23a+39b=6,2\\\dfrac{1}{2}a+\dfrac{1}{2}b=0,1\end{matrix}\right.\\ \Rightarrow a=b=0,1mol\\ \%_{Na}=\dfrac{0,1.23}{6,2}\cdot100=37,1\%\\ \%_K=100-37,1=62,9\%\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ FeO+H_2SO_4\rightarrow FeSO_4+H_2O\\ n_{Zn}=n_{H_2}=0,2mol\\ \%m_{Zn}=\dfrac{0,2.65}{20}\cdot100\%=65\%\\ \%m_{Fe}=100\%-65\%=35\%\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

            \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

a) Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)=n_{Zn}\)

\(\Rightarrow\%m_{Zn}=\dfrac{0,4\cdot65}{36,2}\cdot100\%\approx71,23\%\) \(\Rightarrow\%m_{Al_2O_3}=28,77\%\)

c) Ta có: \(n_{Al_2O_3}=\dfrac{36,2-0,4\cdot65}{102}=0,1\left(mol\right)\)

Theo PTHH: \(n_{HCl}=2n_{Zn}+6n_{Al_2O_3}=1,4\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{1,4\cdot36,5}{10\%}=511\left(g\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{511}{1,1}\approx464,5\left(ml\right)=0,4645\left(l\right)\)

c) Theo PTHH: \(\left\{{}\begin{matrix}n_{ZnCl_2}=0,4\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,4}{0,4645}\approx0,86\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4645}\approx0,43\left(M\right)\end{matrix}\right.\)

a) Đặt \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow24a+27b=5,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Bảo toàn electron: \(2a+3b=0,5\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%\approx47,06\%\\\%m_{Al}=52,94\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,5\cdot36,5}{7,3\%}=250\left(g\right)\)

\(\Rightarrow V_{HCl}=\dfrac{250}{1,2}\approx208,33\left(ml\right)\)

PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,04\left(mol\right)\Rightarrow m_{Zn}=0,04.65=2,6\left(g\right)\)

⇒ m_Cu = 9 - 2,6 = 6,4 (g)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{2,6}{9}.100\%\approx28,89\%\\\%m_{Cu}\approx71,11\%\end{matrix}\right.\)

Đáp án A

Hỗn hợp rắn gồm Al, Al₂O₃, Fe với n Fe = 2 n Al 2 O 3 . Chia thành 2 phần không bằng nhau:

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Zn}=y\end{matrix}\right.\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)

\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)

 x                2x                            x                     x    ( mol )

\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

 y                2y                           y                      y      ( mol )

Ta có:

\(\left\{{}\begin{matrix}24x+65y=11,3\\x+y=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}m_{Mg}=0,2.24=4,8g\\m_{Zn}=0,1.65=6,5g\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{4,8}{11,3}.100=42,47\%\\\%m_{Zn}=100\%-42,47\%=57,53\%\end{matrix}\right.\)

\(m_{CH_3COOH}=60.\left(0,2+0,1\right)=18g\)

\(C\%_{CH_3COOH}=\dfrac{18}{200}.100=9\%\)

\(\left\{{}\begin{matrix}m_{\left(CH_3COO\right)_2Mg}=0,2.142=28,4g\\m_{\left(CH_3COO\right)_2Zn}=0,1.183=18,3g\end{matrix}\right.\)

\(m_{ddspứ}=11,3+200-0,3.2=210,7g\)

\(\rightarrow\left\{{}\begin{matrix}C\%_{\left(CH_3COO\right)_2Mg}=\dfrac{28,4}{210,7}.100=13,47\%\\C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{18,3}{210,7}.100=8,68\%\end{matrix}\right.\)