a)

$Mg + 2HCl \to MgCl_2 + H_2$
$MgO + 2HCl \to MgCl_2 + H_2o$

b)

Theo PTHH : $n_{Mg} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$m_{Mg} = 0,2.24 = 4,8(gam)$

$m_{MgO} = m_{hh} - m_{Mg} = 12,8 - 4,8 = 8(gam)$

c)

$n_{MgO} = \dfrac{8}{40} = 0,2(mol)$
$n_{HCl} = 2n_{Mg} + 2n_{MgO} = 0,8(mol)$

$m_{dd\ HCl} = \dfrac{0,8.36,5}{14,6\%} = 200(gam)$

a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(FeO+2HCl\rightarrow FeCl_2+H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)

⇒ m_FeO = 12,6 - 5,4 = 7,2 (g)

c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?

d, Cho hh vào dd H₂SO₄ đặc nguội thì có khí thoát ra.

PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)

Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)

Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)

\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)

ta có lượng \(H^+\) có trong dung dịch là :

\(n_{H^+}=2n_{H_2SO_4}+n_{HCL}=2\times0,2\times1+0,2\times2=0,8\left(mol\right)\)

a. ta có \(n_{H_2}=\frac{1}{2}n_{H^+}=0,4mol\Rightarrow V_{H_2}=22,4\times0,4=8,96\left(lit\right)\)

b. ta có \(m_{\text{hỗn hợp}}+m_{\text{axit }}=m_{\text{chất tan}}+m_{\text{ khí}}\)

nên \(m_{\text{chất tan }}=12,9+0,2\times98+0,4\times36,5-0,4\times2=46,3\left(g\right)\)

\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)

\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)

a) PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3 H2

x___________3x______________1,5x(mol)

Fe +2 HCl -> FeCl2 + H2

y___2y____y______y(mol)

b) Ta có: m(rắn)= mCu=0,4(g)

=> m(Al, Fe)=1,5-mCu=1,5-0,4=1,1(g)

nH2= 0,04(mol)

Ta lập hpt:

\(\left\{{}\begin{matrix}27x+56y=1,1\\1,5x+y=0,04\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)

=> mAl=27.0,02=0,54(g)

mFe=56.0,01=0,56(g)

Gọi số mol của Al, Mg, CuO là a, b, c

=> 27a + 24b + 80c = 23,8

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

            a---->3a----------------->1,5a

            Mg + 2HCl --> MgCl₂ + H₂

            b----->2b---------------->b

           CuO + 2HCl --> CuCl₂ + H₂O

            c------->2c

=> \(\left\{{}\begin{matrix}1,5a+b=\dfrac{8,96}{22,4}=0,4\\3a+2b+2c=0,6.2=1,2\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}a=0,2\\b=0,1\\c=0,2\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Mg}=0,1.24=2,4\left(g\right)\\m_{CuO}=0,2.80=16\left(g\right)\end{matrix}\right.\)

a) Đặt: nMg=x(mol); nZnO=y(mol)

nH2SO4= 0,2(mol)

PTHH: Mg + H2SO4 -> MgSO4 + H2

x___________x____x_______x(mol)

ZnO + H2SO4 -> ZnSO4 + H2O

y____y______y(mol)

Ta có: 

\(\left\{{}\begin{matrix}24x+81y=12,9\\22,4x=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

mMg=0,2.24=4,8(g)

%mMg=(4,8/12,9).100=37,209%

=>%mZnO=62,791%

b) nH2SO4=x+y=0,3(mol)

=> \(C\%ddH2SO4=\dfrac{0,3.98}{120}.100=24,5\%\)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ a,PTHH:MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\\ MgO+H_2SO_4\rightarrow MgSO_4+H_2O\\ \Rightarrow n_{MgCO_3}=n_{CO_2}=0,1\left(mol\right)\\ \Rightarrow m_{MgCO_3}=0,1\cdot84=8,4\left(g\right)\\ \Rightarrow\%_{MgCO_3}=\dfrac{8,4}{10,4}\cdot100\%\approx80,77\%\\ \Rightarrow\%_{MgO}=100\%-80,77\%=19,23\%\)

\(b,m_{MgO}=10,4-8,4=2\left(g\right)\\ \Rightarrow n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\\ \Rightarrow\sum n_{H_2SO_4}=n_{MgCO_3}+n_{MgO}=0,15\left(mol\right)\\ \Rightarrow\sum m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\\ \Rightarrow\sum m_{dd_{H_2SO_4}}=\dfrac{14,7}{9,8\%}=150\left(g\right)\\ \sum n_{MgSO_4}=\sum n_{H_2SO_4}=0,15\left(mol\right)\\ \Rightarrow\sum m_{MgSO_4}=0,15\cdot120=18\left(g\right)\\ \Rightarrow C\%_{MgSO_4}=\dfrac{18}{10,4+150-0,1\cdot44}\approx11,54\%\)

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