Cu k phản ứng với HCl

\(\rightarrow m_{Cu}=1\left(g\right)\)

\(PTHH:CuO+2HCl\rightarrow CuCl_2+H_2O\)

\(n_{CuO}=\frac{5-1}{80}=0,05\left(mol\right)\)

\(n_{HCl}=1\left(mol\right)\)

\(TL:\frac{1}{2}>\frac{0,05}{1}\rightarrow HCl.du\)

\(C_{M_A}=\frac{0,05}{0,5}=0,1\left(M\right)\)

\(C_{M_{HCl.du}}=\frac{1-0,05.2}{0,5}=1,8\left(M\right)\)

Gọi x, y là số mol của Al và Mg.

27x + 24y = 31,2

Bảo toàn e: 3x + 2y = 2.1,6 = 3,2

Giải hệ thu được: x = 0,8; y = 0,4; mAl = 27.0,2 = 5,4; mMg = 31,2-5,4=25,8g

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl -->ZnCl₂ + H₂

____0,2<----------------------0,2

=> m_Zn = 0,2.65 = 13 (g)

m_Cu = m_{rắn không tan} = 19,5 (g)

\(\left\{{}\begin{matrix}\%Zn=\dfrac{13}{13+19,5}.100\%=40\%\\\%Cu=\dfrac{19,5}{13+19,5}.100\%=60\%\end{matrix}\right.\)

`n_(H_2)=4,48/22,4=0,2 (mol)`

Ta có PTHH: `Zn+2HCl --> ZnCl_2 +H_2`

Theo PT:       `1`--------------------------------`1`

Theo đề:       `0,2`------------------------------`0,2`

`m_(Zn)=0,2.65=13(g)`

Vì `Cu` không phản ứng với `HCl` nên `m_(chất rắn không tan)=m_(Cu)=19,5(gam)`

`%Zn=13/(13+19,5) .100%=40%`

`%Cu=100%-40%=60%`

a, \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

m_{hh Zn và Fe} = 21,6-3 = 18,6 (g)

PTHH: Zn + H₂SO₄ → ZnSO₄ + H₂

Mol:      x                                           x

PTHH: Fe + H₂SO₄ → FeSO₄ + H₂

Mol:      y                                           y 

Ta có: \(\left\{{}\begin{matrix}65x+56y=18,6\\x+y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\%m_{Zn}=\dfrac{0,2.65.100\%}{21,6}=60,19\%\)

\(\%m_{Fe}=\dfrac{0,1.56.100\%}{21,6}=25,93\%\)

\(\%m_{Cu}=100-60,19-25,93=13,88\%\)

b,

PTHH: Zn + H₂SO₄ → ZnSO₄ + H₂

Mol:     0,2     0,2                            0,2

PTHH: Fe + H₂SO₄ → FeSO₄ + H₂

Mol:     0,1      0,1                            0,1 

\(m_{H_2SO_4}=\left(0,1+0,2\right).98=29,4\left(g\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{29,4.100\%}{25\%}=117,6\left(g\right)\)

c,m_{dd sau pư} = 21,6+117,6- (0,1+0,2).2 = 138,6 (g)

\(C\%_{ddZnSO_4}=\dfrac{0,2.161.100\%}{138,6}=23,23\%\)

\(C\%_{ddFeSO_4}=\dfrac{0,1.152.100\%}{138,6}=10,97\%\)

Đề yêu cầu tính gì vậy bạn

Câu 1:

\(PTHH:Zn+2HCl\to ZnCl_2+H_2\\ m_{Zn}=29-16=13(g)\\ \Rightarrow n_{Zn}=\dfrac{13}{65}=0,2(mol)\\ \Rightarrow a=n_{HCl}=2n_{Zn}=0,4(mol)\\ n_{Cu}=\dfrac{16}{64}=0,25(mol)\\ \Rightarrow \%_{n_{Zn}}=\dfrac{0,2}{0,2+0,25}.100\%=44,44\%\\ \Rightarrow \%_{n_{Cu}}=100\%-44,44\%=55,56\%\)

Câu 2:

Đặt \(n_{Al}=x(mol);n_{Mg}=y(mol)\Rightarrow 27x+ 24y=9,9(1)\)

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45(mol)\\ PTHH:2Al+6HCl\to 2AlCl_3+3H_2\\ Mg+2HCl\to MgCl_2+H_2\\ \Rightarrow 1,5x+y=0,45(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,3(mol)\\ \Sigma n_{HCl(p/ứ)}=3x+2y=0,9(mol)\\ \Rightarrow a=n_{HCl(tt)}=0,9.120\%=1,08(mol)\\ \%_{Mg}=\dfrac{0,3.24}{9,9}.100\%=72,73\%\\ \%_{Al}=100\%-72,73\%=27,27\%\)

a. PTHH:

\(Cu+H_2SO_4--\times-->\)

\(CuO+H_2SO_4--->CuSO_4+H_2O\left(1\right)\)

\(Cu+2H_2SO_{4_{đặc}}\overset{t^o}{--->}CuSO_4+SO_2+2H_2O\left(2\right)\)

Ta có: \(n_{SO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

Theo PT₍₂₎: \(n_{Cu}=n_{SO_2}=0,05\left(mol\right)\)

\(\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)

\(\Rightarrow\%_{m_{Cu}}=\dfrac{3,2}{10}.100\%=32\%\)

\(\%_{m_{CuO}}=100\%-32\%=68\%\)

\(a)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=0,1mol\\ m_{Zn}=0,1.65=6,5g\\ m_{Cu}=9,7-6,5=3,2g\\ b)C_{\%ZnCl_2}=\dfrac{0,1.136}{6,5+120-0,1.2}\cdot100=10,77\%\)