a) \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b) Gọi x,y là số mol Al, Fe

\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)

Ta có hệ : \(\left\{{}\begin{matrix}27x+56y=0,83\\\dfrac{3}{2}x+y=0,02\end{matrix}\right.\)

=> \(x=\dfrac{29}{5700};y=\dfrac{47}{3800}\)

\(\%m_{Al}=\dfrac{\dfrac{27}{5700}.27}{0,83}.100=16,55\%\); \(\%m_{Fe}=100-16,55=83,45\%\)

c)Bảo toàn nguyên tố H: \(n_{H_2SO_4}=n_{H_2}=0,02\left(mol\right)\)

=> \(C\%_{H_2SO_4}=\dfrac{0,02.98}{200}.100=0,98\%\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(n_{H_2}=n_{Fe}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)

\(m_{CuO}=35.2-0.2\cdot56=24\left(g\right)\)

\(n_{CuO}=\dfrac{24}{80}=0.3\left(mol\right)\)

\(\%Fe=\dfrac{11.2}{35.2}\cdot100\%=31.82\%\)

\(\%CuO=100-31.82=68.18\%\)

\(n_{H_2SO_4}=0.2+0.3=0.5\left(mol\right)\)

\(m_{H_2SO_4}=0.5\cdot98=49\left(g\right)\)

\(C\%H_2SO_4=\dfrac{49}{800}\cdot100\%=6.125\%\)

\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)

\(m_{CuSO_4}=0.3\cdot160=48\left(g\right)\)

a, Ta có: 27n_Al + 56n_Fe = 0,83 (1)

PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow n_{Al}=n_{Fe}=0,01\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%\approx32,53\%\\\%m_{Fe}\approx67,47\%\end{matrix}\right.\)

b, n_H2SO4 = n_H2 = 0,025 (mol)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,025.98}{20\%}=12,25\left(g\right)\)

Đáp án C.

Kim loại không phản ứng với H₂SO₄ loãng là Cu.

Gọi n_Cu = x, n_Mg = y, n_Al = z

Ta có:

64x + 24y + 27z = 33,2 (1)

Bảo toàn e:

2n_Mg + 3n_Al = 2n_H2  

=> 2y + 3z = 2.1 (2)

2n_Cu = 2n_SO2  =>  x = 0.2 (mol) (3)

Từ 1, 2, 3 => x = 0,2; y = z = 0,4 (mol)

m_Cu = 0,2.64 = 12,8 (g)

m_Mg = 0,4.24 = 9,6 (g)

m_Al = 10,8 (g)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

x                                            x

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

y                                                 3/2y

\(nH_2=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

ta có hệ pt:

\(\left\{{}\begin{matrix}x+\dfrac{3}{2}y=0,4\\24x+27y=7,8\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(mMg=0,1.24=2,4\left(g\right)\)

\(mAl=0,2.27=5,4\left(g\right)\)