Câu 1:

a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)

\(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)

c, \(n_{HCl}=2n_{Zn}=0,5\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,5.36,5=18,25\left(g\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{18,25}{10\%}=182,5\left(g\right)\)

d, \(n_{ZnCl_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow C\%_{ZnCl_2}=\dfrac{0,25.136}{16,25+182,5-0,25.2}.100\%\approx17,15\%\)

Câu 2:

a, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

c, \(n_{NaOH}=\dfrac{40}{40}=1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow V_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(l\right)\)

d, \(n_{Na_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,25}=2\left(M\right)\)

a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(n_{H_2}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\Rightarrow m_{Al}=0,4.27=10,8\left(g\right)\)

b, \(n_{HCl}=2n_{H_2}=1,2\left(mol\right)\Rightarrow C\%_{HCl}=\dfrac{1,2.36,5}{250}.100\%=17,52\%\)

c, m _{dd sau pư} = 10,8 + 250 - 0,6.2 = 259,6 (g)

d, \(n_{AlCl_3}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow C\%_{AlCl_3}=\dfrac{0,4.133,5}{259,6}.100\%\approx20,57\%\)

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

a)PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

b) \(n_{Mg}=n_{H_2}=0,15\left(mol\right)\)

\(m_{Mg}=0,15.24=3,6\left(g\right)\)

c) \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)

\(C_{M_{HCl}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\)

a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{FeCl_2}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)

b, \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,15}=4\left(M\right)\)

c, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)

Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,6\left(mol\right)\)

\(\Rightarrow V_{NaOH}=\dfrac{0,6}{1}=0,6\left(l\right)=600\left(ml\right)\)

\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe,pư}=n_{FeCl_2}=n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ m_{Fe,pư}=0,3.56=16,8g\\ b.n_{HCl}=0,3.2=0,6mol\\ C_{M_{HCl}}=\dfrac{0,6}{0,15}=4M\\ c.2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\\ n_{NaOH}=0,3.2=0,6mol\\ V_{ddNaOH}=\dfrac{0,6}{1}=0,6l=600ml\)

a) \(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)

PTHH: MgCO₃ + 2HCl ---> MgCl₂ + CO₂ + H₂O

            0,2--------------------->0,2----->0,2

=> \(m=m_{MgCl_2}=0,2.95=19\left(g\right)\)

\(m_{\text{dd}.sau.p\text{ư}}=150+16,8-0,2.44=158\left(g\right)\)

=> \(C\%_{MgCl_2}=\dfrac{19}{158}.100\%=12,025\%\)

b) CO₂ + Ca(OH)₂ ---> CaCO₃ + H₂O

     0,2----->0,2------------>0,2

=> \(\left\{{}\begin{matrix}m_{kt}=m_{CaCO_3}=0,2.100=20\left(g\right)\\V_{\text{dd}Ca\left(OH\right)_2}=\dfrac{0,2}{3}=\dfrac{1}{15}\left(l\right)\end{matrix}\right.\)

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

n Al=0,25 mol

2Al + 6HCl → 2AlCl₃ + 3H₂

0,25---0,75------0,25------0,375 mol

=>VH2=0,375.22,4=8,4l

=>m AlCl3=0,25.133,5=33,375g

=>CM HCl=\(\dfrac{0,75}{2}\)=0,375M

Chắc là Na2CO3 chứ em nhỉ?

nNa2CO3= 0,02 (mol)

nHCl= 0,6(mol)

PTHH: Na2CO3 + 2 HCl -> 2 NaCl + CO2 + H2O

Ta có: 0,02/1 < 0,6/3

=> HCl dư, Na2CO3 hết, tính theo nNa2CO3.

nCO2= 0,02/2= 0,01(mol)

=> V(CO2,đktc)=0,01.22,4= 0,224(l)

Các chất sau phản ứng gồm: NaCl và HCl (dư)

nNaCl= 2.0,02=0,04(mol)

nHCl(dư)=0,6-0,02.2=0,56(mol)

Anh nghĩ đề nên có cho thêm khối lượng riêng Na2CO3 để tính thể tích mà cộng vào tính thể tích dung dịch sau p.ứ