\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ PTHH:2NaOH+H_2SO_4\to Na_2SO_4+2H_2O\\ a,n_{NaOH}=0,4(mol);n_{Na_2SO_4}=0,2(mol)\\ \Rightarrow \begin{cases} m_{Na_2SO_4}=0,2.142=28,4(g)\\ m_{dd_{NaOH}}=\dfrac{0,4.40}{20\%}=80(g) \end{cases}\\ b,2KOH+H_2SO_4\to K_2SO_4+2H_2O\\ \Rightarrow n_{KOH}=0,4(mol)\\ \Rightarrow m_{dd_{KOH}}=\dfrac{0,4.56}{5,6\%}=400(g)\\ \Rightarrow V_{dd_{KOH}}=\dfrac{400}{1,045}=382,78(ml)\)

Bước 1: nH2SO4 = VH2SO4 . CM H2SO4= 0,2 . 1 = 0,2mol

Bước 2:

PTHH:       2NaOH    +    H2SO4 →  Na2SO4 + H2O

                     2 mol             1 mol     

                    ? mol               0,2mol

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{H_2SO_4}=0.3\cdot0.5=0.15\left(mol\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.1..........0.05...............0.05\)

Dung dịch D : 0.05 (mol) K₂SO₄ , 0.1 (mol) H₂SO₄

\(\left[K^+\right]=\dfrac{0.05\cdot2}{0.1+0.3}=0.25\left(M\right)\)

\(\left[H^+\right]=\dfrac{0.1\cdot2}{0.1+0.3}=0.5\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.1}{0.1+0.3}=0.375\left(M\right)\)

\(2NaOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.2..................0.1\)

\(V_{dd_{NaOH}}=\dfrac{0.2}{1}=0.2\left(l\right)\)

a) \(n_{NaOH}=0,2.1=0,2\left(mol\right)\); \(n_{HNO_3}=0,2.0,5=0,1\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

0,2.............0,1

Lập tỉ lệ : \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\) => Sau phản ứng NaOH dư

Dung dịch D gồm NaNO3 và NaOH dư

\(n_{NaNO_3}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(pứ\right)}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)

Ion trong dung dịch D : Na+ , NO3-, OH-

\(\left[Na^+\right]=\dfrac{0,1+0,1}{0,2}=1M\)

\(\left[NO_3^-\right]=\dfrac{0,1}{0,2}=0,5M\)

\(\left[OH^-\right]=\dfrac{0,1}{0,2}=0,5M\)

b)Trong dung dịch D chỉ có NaOH dư phản ứng

 \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

0,1................0,05

=> \(V_{H_2SO_4}=\dfrac{0,05}{1}=0,05\left(l\right)\)

Tách ra lần bài đi em !

Đáp án : C

Bảo toàn e : 2n_H2 = 3n_Al+ + 2n_Fe2+ = 0,5 mol

=> n_{H+ dư} = n_HCl + 2n_H2SO4 – 2n_H2 = 0,1 mol

Để đạt kết tủa lớn nhất : n_OH = n_H+ + 3n_Al+ + 2n_Fe2+ = 0,6 mol

=> V_{dd NaoH} = 0,6 lit = 600 ml

NaOH + HCl --> NaCl+H2O (1)

2NaOH +H2SO4 --> Na2SO4 +2H2O (2)

Đặt n_{NaOH (1)}= a(mol)

n_NaOH(2) = b (mol)

=>a + b = 0,3.2 =0,6( *)

Theo PT (1) : n_NaCl = n_NaOH(1) = a(mol)

Theo PT (2) : n_Na2SO4=\(\dfrac{1}{2}\) n_NaOH(2) = 0,5b(mol)

=>58,5a + 71b =40,1(**)

Từ (*), (**) => a= 0,2 ; b = 0,4 

 n_HCl = n_{NaOH (1)}=0,2 mol 

=> \(x=CM_{HCl}=\dfrac{0,2}{0,2}=1M\)

n_H2SO4 = n_{NaOH (2)}=0,4 mol 

\(y=CM_{H_2SO_4}=\dfrac{0,4}{0,2}=2M\)

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left[OH^-\right]=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02........0.02\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.02}{1}=0.02\left(l\right)\)

\(a.\)

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^+\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02.......0.02\)

\(V_{H_2SO_4}=\dfrac{0.02}{1}=0.02\left(l\right)\)

a) Ta có: \(n_{NaOH}=0,1\cdot0,1=n_{KOH}=0,01\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{OH^-}=0,02\left(mol\right)\\n_{Na^+}=n_{K^+}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\left[OH^-\right]=\dfrac{0,02}{0,2}=0,1\left(M\right)\\\left[Na^+\right]=\left[K^+\right]=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)

b) Ta có: \(pH=14+log\left[OH^-\right]=13\)

c) PT ion: \(OH^-+H^+\rightarrow H_2O\)

Theo PT ion: \(n_{H^+}=n_{OH^-}=0,02\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4}=0,01\left(mol\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,01}{1}=0,01\left(l\right)=10\left(ml\right)\)