Tk

2Ca + O₂ -> 2CaO (1)

CaO + 2HCl -> CaCl₂ + H₂O (2)

n_Ca=0,4(mol)

n_HCl=0,5(mol)

Từ 1:

n_CaO=n_Ca=0,4(mol)

Vì 1212n_HCl=0,25(mol)

m_CaCl2=111.0,25=27,75(g)

m_CaO=56.0,15=8,4(g)

\(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)

a) Pt : \(CuO+2HCl\rightarrow CuCl_2+H_2O|\)

             1            2             1            1

             0,1        0,2           0,1

b) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)

⇒ \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)

\(C_{ddHCl}=\dfrac{7,3.100}{200}=3,65\)⁰/₀

c) \(n_{CuCl2}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)

⇒ \(m_{CuCl2}=0,1.135=13,5\left(g\right)\)

 Chúc bạn học tốt

\(a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2(mol)\)

Vì \(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\) nên Zn dư

\(\Rightarrow n_{Zn({\text{phản ứng})}}=\dfrac{1}{2}n_{HCl}=0,15(mol)\\ \Rightarrow n_{Zn(\text{dư})}=0,2-0,15=0,05(mol)\\ \Rightarrow m_{Zn(\text{dư})}=0,05.65=3,25(g)\\ c,n_{ZnCl_2}=n_{H_2}=\dfrac{1}{2}n_{HCl}=0,15(mol)\\ \Rightarrow a=m_{ZnCl_2}=0,15.136=20,4(g)\\ V=V_{H_2}=0,15.22,4=3,36(l)\)

3,36

\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ Ta.c\text{ó}:\dfrac{0,2}{1}>\dfrac{0,3}{2}\Rightarrow Zn.d\text{ư}\\ b,n_{Zn\left(d\text{ư}\right)}=0,2-\dfrac{0,3}{2}=0,05\left(mol\right)\\ \Rightarrow m_{Zn\left(d\text{ư}\right)}=0,05.65=3,25\left(g\right)\\ c,a=m_{ZnCl_2}=0,15.136=20,4\left(g\right)\\ V=V_{H_2\left(\text{đ}ktc\right)}=0,15.22,4=3,36\left(l\right)\)

\(n_{Ca}=\dfrac{8}{40}=0,2mol\\ 2Ca+O_2\xrightarrow[]{t^0}2CaO\\ n_{CaO}=n_{Ca}=0,2mol\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ \Rightarrow\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCl.dư\\ n_{CaCl_2}=n_{CaO}=0,2mol\\ n_{HCl}=2n_{CaO}=0,4mol\\ m_{CaCl_2}=0,2.111=22,2g\\ m_{HCl.dư}=\left(0,5-0,4\right).36,5=3,65g\)

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

\(n_{NaOH}=\dfrac{20\%.200}{40}=1\left(mol\right)\\ NaOH+HCl\rightarrow NaCl+H_2O\\ n_{NaCl}=n_{HCl}=n_{NaOH}=1\left(mol\right)\\ a,m_{ddNaCl}=200+100=300\left(g\right)\\ C\%_{ddNaCl}=\dfrac{58,5.1}{300}.100=19,5\%\\ b,C\%_{ddHCl}=\dfrac{36,5.1}{100}.100=36,5\%\)

`a) PTPƯ: CuO + H_2 SO_4 -> CuSO_4 + H_2 O`

`b) n_[CuO] = [ 1,6 ] / 80 = 0,02 (mol)`

    `n_[H_2 SO_4] = [ 20 / 100 . 100 ] / 98 = 10 / 49 (mol)`

Ta có: `[ 0,02 ] / 1 < [ 10 / 49 ] / 1`

      `-> CuO` hết ; `H_2 SO_4` dư

Theo `PTPƯ` có : `n_[H_2 SO_4\text{ p/ư}] = n_[CuO] = n_[CuSO_4] = 0,02 (mol)`

 `@ C%_[H_2 SO_4\text{ dư}] = [ 10 / 49 - 0,02 ] / [ 1,6 + 100 ] . 100 ~~ 0,2 %`

 `@ C%_[CuSO_4] = [ 0,02 ] / [ 1,6 + 100 ] . 100 ~~ 0,02 %`

a. Ta có: \(n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\)

Ta lại có: \(C_{\%_{HCl}}=\dfrac{m_{ct_{HCl}}}{100}.100\%=7,3\%\)

=> m_HCl = 7,3(g)

=> \(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)

PTHH:

Fe₃O₄ + 8HCl ---> FeCl₂ + 2FeCl₃ + 4H₂O

    1   --->   8

    0,1 --->  0,2

=> \(\dfrac{0,1}{1}>\dfrac{0,2}{8}\)

Vậy Fe₃O₄ dư

=> m_dư = 23,2 - 7,3 = 15,9 (g)

b. Theo PT: \(n_{FeCl_2}=\dfrac{1}{8}.n_{HCl}=\dfrac{1}{8}.0,2=0,025\left(mol\right)\)

=> \(m_{FeCl_2}=0,025.127=3,175\left(g\right)\)

Theo PT: \(n_{FeCl_3}=\dfrac{1}{4}.n_{HCl}=\dfrac{1}{4}.0,2=0,05\left(mol\right)\)

=> \(m_{FeCl_3}=0,05.162,5=8,125\left(g\right)\)

=> \(m_{muối}=8,125+3,175=11,3\left(g\right)\)

c. Ta có: m_{dung dịch sau PỨ} = \(23,2+100=123,2\left(g\right)\)

Theo PT: \(n_{H_2O}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\)

=> \(m_{H_2O}=0,1.18=1,8\left(g\right)\)

m_{các chất sau PỨ} = 1,8 + 11,3 = 13,1(g)

=> \(C_{\%_{sauPỨ}}=\dfrac{13,1}{123,2}.100\%=10,63\%\)