n_Ba = \(\frac{54,8}{137}\) = 0,4 (mol)

n_CuSO4 = \(\frac{800.3,2\%}{160}\) = 0,16 (mol)

Ba + 2 H₂O \(\rightarrow\) Ba(OH)₂ + H₂ \(\uparrow\)

0,4 -------------> 0,4 ------> 0,4 (mol)

Ba(OH)₂ + CuSO₄ \(\rightarrow\) BaSO₄ \(\downarrow\) + Cu(OH)₂ \(\downarrow\)

bđ 0,4 .......... 0,16 (mol)

pư 0,16 <------ 0,16 -----> 0,16 ------> 0,16 (mol)

spư 0,24 ....... 0 .............. 0,16 .......... 0,16 (mol)

Khí A : H₂ : 0,4 mol

Kết tủa B: \(\begin{cases}BaSO_4:0,16mol\\Cu\left(OH\right)_2:0,16mol\end{cases}\)

dd C: Ba(OH)₂ : 0,24 mol

a)V_H2 = 0,4 . 22,4 = 8,96 (mol)

b) Cu(OH)₂ \(\underrightarrow{t^0}\) CuO + H₂O

0,16 ------------> 0,16 (mol)

CR thu đc sau pư: \(\begin{cases}BaSO_4:0,16mol\\CuO:0,16mol\end{cases}\)

m_CR = 0,16 . 233 + 0,16 . 80 = 50,08 (g)

c) m_dd = 54,8 + 800 - 0,4 . 2 - 50,08 = 803,92 (g)

C%(Ba(OH)₂)= \(\frac{0,24.171}{803,92}\) . 100% = 5,1%

Pt: Ba+2H₂O -> Ba(OH)₂+H₂ (1)

Ba(OH)₂+CuSO₄ ->Cu(OH)₂ \(\downarrow\) +BaSO₄ \(\downarrow\)(2)

Ba(OH)₂+(NH₄)₂SO₄ ->BaSO₄ \(\downarrow\)+2NH₃+2H₂O (3)

Cu(OH)₂\(\underrightarrow{t^0}\)CuO+H₂O (4)

BaSO₄ \(\underrightarrow{t^0}\) ko xảy ra phản ứng

Theo (1) ta có \(n_{H_2}=n_{Ba\left(OH\right)_2}=n_{Ba}=\frac{27,4}{137}=0,2\left(mol\right)\)

\(n_{\left(NH_4\right)_2SO_4}=\frac{1,32\cdot500}{132\cdot100}=0,05\left(mol\right)\)

\(n_{CuSO_4}=\frac{2\cdot500}{100\cdot160}=0,0625\left(mol\right)\)

Ta thấy: \(n_{Ba\left(OH\right)_2}>n_{\left(NH_4\right)_2SO_4}+n_{CuSO4\:}\) nên Ba(OH)₂ dư và 2 muối đều phản ứng hết

Theo (2) ta có: \(n_{Ba\left(OH\right)_2}=n_{Cu\left(OH\right)_2}=n_{BaSO_4}=n_{CuSO_4}=0,0625\left(mol\right)\)

Theo (3) ta có: \(n_{Ba\left(OH\right)_2}=n_{BaSO_4}=n_{\left(NH_4\right)_2SO_4}=0,05\left(mol\right)\)

và \(n_{NH_3}=2n_{\left(NH_4\right)_2SO_4}=0,05\cdot2=0,1\left(mol\right)\)

\(\Rightarrow n_{Ba\left(OH_2\right)}\text{dư}=0,2-\left(0,05+0,0625\right)=0,0875\left(mol\right)\)

a)\(V_{A\left(ĐKTC\right)}=V_{H_2}+V_{NH_3}=\left(0,2+0,1\right)\cdot22,4=6,72\left(l\right)\)

b)Theo (4) ta có: \(n_{CuO}=n_{Cu\left(OH\right)_2}=0,0625\left(mol\right)\)

\(m_{\text{chất rắn}}=m_{BaSO_4}+m_{CuO}=\left(0,0625+0,05\right)\cdot233+0,0625\cdot80=31,2125\left(g\right)\)

Ta có: \(n_K=\dfrac{1,56}{39}=0,04\left(mol\right)\)

\(m_{CuSO_4}=200.8\%=16\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)

PT: \(2K+2H_2O\rightarrow2KOH+H_2\)

___0,04___________0,04___0,02 (mol)

 \(2KOH+CuSO_4\rightarrow K_2SO_4+Cu\left(OH\right)_{2\downarrow}\)

Xét tỉ lệ: \(\dfrac{0,04}{2}< \dfrac{0,1}{1}\), ta được CuSO₄ dư.

Theo PT: \(n_{Cu\left(OH\right)_2}=n_{CuSO_4\left(pư\right)}=n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,02\left(mol\right)\)

⇒ n_{CuSO4 (dư)} = 0,08 (mol)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

___0,02____0,02 (mol)

a, Ta có: V_B = 0,02.22,4 = 0,448 (l)

b, m_CuO = 0,02.80 = 1,6 (g)

c, Ta có: m _{dd sau pư} = 1,56 + 200 - 0,02.2 - 0,02.98 = 199,56 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{0,02.174}{199,56}.100\%\approx1,74\%\\C\%_{CuSO_4\left(dư\right)}=\dfrac{0,08.160}{199,56}.100\%\approx6,41\%\end{matrix}\right.\)

Bạn tham khảo nhé!

\(n_K=\dfrac{1,56}{39}=0,04\left(mol\right)\)

\(n_{CuSO4}=\dfrac{200.8}{100.160}=0,1\left(mol\right)\)

\(2K+2H2O\rightarrow2KOH+H2\)

0,04--------------->0,04------------->0,02(mol)

\(2KOH+CuSO4\rightarrow Cu\left(OH\right)2+K2SO4\)

0,04-------->0,02----->0,02------->0,02(mol)

=> dd A gồm CuSO4 dư và K2SO4

=> Khí B là H2

=>Kết tủa C là Cu(OH)2

a) \(V_{H2}=0,02.22,4=0,448\left(l\right)\)

b)\(Cu\left(OH\right)2\rightarrow CuO+H2O\)

0,02---------------->0,02(mol)

\(m_{CuO}=0,02.80=1,6\left(g\right)\)

c) \(m_{KOH}=0,04.56=2,24\left(g\right)\)

\(m_{Cu\left(OH\right)2}=0,02.98=1,96\left(g\right)\)

\(\Rightarrow\)\(m_{dd}=200+2,24-1,96=200,28\left(g\right)\)

\(C\%_{K2SO4}=\dfrac{0,02.174}{200,28}.100\%=1,74\%\)

\(n_{CuSO4}dư=0,1-0,02=0,08\left(mol\right)\)

\(C\%_{CuSO4}=\dfrac{0,08.160}{200,28}.100\%=6,39\%\)

Chúc bạn học tốt^^