\(n_{CuO}=2a\left(mol\right)\Rightarrow n_{Fe_2O_3}=a\left(mol\right)\)

\(m_X=80\cdot2a+160a=80\left(g\right)\)

\(\Rightarrow a=0.25\left(mol\right)\)

\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)

\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)

\(n_{H_2}=0.5+0.25\cdot3=1.25\left(mol\right)\)

\(V_{H_2}=1.25\cdot22.4=28\left(l\right)\)

\(m_{cr}=0.5\cdot64+0.5\cdot56=60\left(g\right)\)

Gọi \(n_{Fe_3O_4}=a\left(mol\right)\rightarrow n_{Cu}=3a\left(mol\right)\)

\(232a+64.3a=21,2\\ \Leftrightarrow a=0,05\left(mol\right)\)

\(m_{HCl}=125.14,6\%=18,25\left(g\right)\)

PTHH:

Fe₃O₄ + 8HCl ---> FeCl₂ + 2FeCl₃ + 4H₂O

0,05------>0,4------->0,05---->0,1

\(m_X=0,05.3.64=9,6\left(g\right)\)

\(m_{dd}=232.0,05+125=136,6\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,05.127}{136,6}.100\%=4,65\%\\C\%_{FeCl_3}=\dfrac{0,1.162,5}{136,6}.100\%=11,9\%\\C\%_{HCl\left(dư\right)}=\dfrac{18,25-0,4.36,5}{136,6}=2,67\%\end{matrix}\right.\)

a) \(\left\{{}\begin{matrix}160n_{Fe_2O_3}+80n_{CuO}=24\\n_{Fe_2O_3}=n_{CuO}\end{matrix}\right.\Rightarrow n_{Fe_2O_3}=n_{CuO}=0,1\)

\(\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{160.0,1}{24}.100\%=66,67\%\\\%m_{CuO}=\dfrac{80.0,1}{24}.100\%=33,33\%\end{matrix}\right.\)

PTHH: Fe₂O₃ + 3H₂SO₄ --> Fe₂(SO₄)₃ + 3H₂O

              0,1------>0,3-------->0,1

            CuO + H₂SO₄ --> CuSO₄ + H₂O

              0,1-->0,1---------->0,1

n_CuSO4 = 0,1 (mol)

n_Fe2(SO4)3 = 0,1 (mol)

=> m = 0,1.160 + 0,1.400 = 56(g)

b) \(m_{H_2SO_4\left(pthh\right)}=\left(0,3+0,1\right).98=39,2\left(g\right)\)

=> m_{H2SO4(thực tế)} = \(\dfrac{39,2.125}{100}=49\left(g\right)\)

c) \(n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\)

=> n_BaSO4 = 0,5 (mol)

=> m_BaSO4 = 0,5.233 = 116,5(g)

Y tác dụng NaOH cho khí hydrogen nên Y có Al dư.

\(2Al+Fe_2O_3-t^0>Al_2O_3+2Fe\\ Y:Al_{dư}\left(a\left(mol\right)\right),Fe\left(2b\left(mol\right)\right),Al_2O_3\left(b\left(mol\right)\right)\\ n_{H_2}=\dfrac{3}{2}a+2b=0,4\\ n_{Al\left(dư\right)}=\dfrac{2}{3}n_{H_2}=0,2mol=a\\ b=0,05mol\\ BTKL:m=27a+56\cdot2b+102b=16,1g\)

\(n_{H_2SO_4}=0,25.2=0,5\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{Al_2O_3}=x\left(mol\right)\\n_{CuO}=y\left(mol\right)\end{matrix}\right.\)

\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)

 x----------> 3x --------> x 

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

y --------> y -------->  y

Có hệ phương trình

\(\left\{{}\begin{matrix}102x+80y=26,2\\3x+y=0,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\%_{m_{Al_2O_3}}=\dfrac{102.0,1.100}{26,2}=38,93\%\)

\(\%_{m_{CuO}}=\dfrac{80.0,2.100}{26,2}=61,07\%\)

\(CM_{Al_2\left(SO_4\right)_3}=\dfrac{x}{0,25}=\dfrac{0,1}{0,25}=0,4M\)

\(CM_{CuSO_4}=\dfrac{y}{0,25}=\dfrac{0,2}{0,25}=0,8M\)

Đáp án : B

CO không phản ứng với MgO => Chất rắn gồm MgO ; Fe : 0,3 mol ; Cu

Chỉ có Fe phản ứng với H₂SO₄ loãng sinh ra khí H₂

=> n_H2 = n_Fe = 0,3 mol => V = 6,72 lit