a) Phương trình hóa học của phản ứng:

b) Theo pt (1): nCl2 = nMnCl2 = nMnO2 = 0,8 mol

Theo pt (2): nNaCl = nNaClO = nCl2 = 0,8 mol

nNaOH pư = 2. nCl2 = 2. 0,8 = 1,6 mol

⇒ nNaOH dư = 2 - 1,6 = 0,4 mol

Nồng độ mol/l của các chất trong dung dịch sau phản ứng:

CM (NaCl) = CM (NaClO) = CM(MnCl2) =  = 1,6 mol/ lit

CM (NaOH)dư =  = 0,8 mol/ lit

\(a,\left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\\ PTHH:H_2SO_4+BaCl_2\rightarrow2HCl+BaSO_4\downarrow\)

Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên sau phản ứng \(H_2SO_4\) dư

\(\Rightarrow n_{BaSO_4}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\)

\(b,n_{HCl}=2n_{BaCl_2}=0,5\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,5\cdot36,5=18,25\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{18,25}{441,75}\cdot100\%\approx4,13\%\)

a) \(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: CaCO₃ + 2HCl ---> CaCl₂ + CO₂ + H₂O

             0,3<-----0,6<------------------0,3

=> m = 0,3.100 = 30 (g)

b) \(C\%_{HCl}=\dfrac{0,6.36,5}{150}.100\%=14,6\%\)

\(a,PTHH:H_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2HCl\\ \left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\)

Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên H₂SO₄ dư

\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\\ b,n_{HCl}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,25\cdot36,5=9,125\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{9,125}{441,75}\cdot100\%\approx2,07\%\)

nH2SO4 = nBaSO4 = 0,1

-> y = 0,2 (mol/l)

nAl2O3 = 0,01

TH1: Axit dư:

     H2SO4 + 2NaOH —> Na2SO4 + 2H2O
        0,25x        0,5x

     3H2SO4 + Al2O3 —> Al2(SO4)3 + 3H2O
        0,03          0,01

-> nH2SO4 = 0,25x + 0,03 = 0,1

-> x = 0,28 (mol/l)

TH2: NaOH dư:

     H2SO4 + 2NaOH —> Na2SO4 + 2H2O

          0,1        0,2

     Al2O3 + 2NaOH —> 2NaAlO2 + H2O

       0,01          0,02

-> nNaOH tổng = 0,5x = 0,22

-> x = 0,44 (mol/l)

 Vậy   \(\left[{}\begin{matrix}x=0,28\\x=0,44\end{matrix}\right.\)(mol/l)

       y = 0,2 (mol/l)

Đáp án D

→ 0,015.35,5 + 0,2a.137 + 17(0,4a - 0,015) = 1,9875

→ a = 0,05 M

Đáp án D

Ta có: \(n_{H_2SO_4\left(1\right)}=0,2.1=0,2\left(mol\right)\)

\(n_{H_2SO_4\left(2\right)}=0,5.3=1,5\left(mol\right)\)

\(\Rightarrow\Sigma n_{H_2SO_4}=0,2+1,5=1,7\left(mol\right)\)

\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{1,7}{0,2+0,5}\approx2,4M\)

Bạn tham khảo nhé!

Mọi người giúp mình giải bài này vs

a, \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)

b, \(n_{CO_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{CO_2}=0,08\left(mol\right)\)

\(\Rightarrow C_{M_{HCl}}=\dfrac{0,08}{0,2}=0,4\left(M\right)\)

c, \(n_{Na_2CO_3}=0,04\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na_2CO_3}=\dfrac{0,04.106}{10}.100\%=42,4\%\\\%m_{NaCl}=57,6\%\end{matrix}\right.\)