\(4.\)

\(n_{H_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(0.15.....0.3....................0.15\)

\(m_{Fe}=0.15\cdot56=8.4\left(g\right)\)

\(C_{M_{HCl}}=\dfrac{0.3}{0.5}=0.6\left(M\right)\)

\(5.\)

\(Đặt:n_{Fe}=a\left(mol\right),n_{Al}=b\left(mol\right)\)

\(m_{hh}=56a+27b=8.3\left(g\right)\left(1\right)\)

\(n_{H_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\Rightarrow a+1.5b=0.25\left(2\right)\)

\(\left(1\right),\left(2\right):a=b=0.1\)

\(\%Fe=\dfrac{5.6}{8.3}\cdot100\%=67.47\%\)

\(\%Al=32.53\%\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right);n_{SO_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)

PTHH: 

Fe + 2HCl ---> FeCl₂ + H₂ 

0,2------------------------>0,2

\(2Fe+6H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)

0,2---------------------------------------->0,3

\(Cu+2H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}CuSO_4+SO_2+2H_2O\)

0,15<--------------------------------0,15

=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2.56}{0,2.56+0,15.64}.100\%=53,85\%\\\%m_{Cu}=100\%-53,85\%=46,15\%\end{matrix}\right.\)

a) Gọi số mol Mg, Al, Fe trong m gam hỗn hợp là a, b, c (mol)

\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

_______a--------------------->a------->a_______(mol)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

_b-------------------->b------->1,5b___________(mol)

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

_c------------------>c------->c_______________(mol)

=> \(\left\{{}\begin{matrix}a+1,5b+c=0,35\left(1\right)\\95a+133,5b+127c=35,55\left(2\right)\end{matrix}\right.\)

Mặt khác:

PTHH: \(Mg+Cl_2\underrightarrow{t^o}MgCl_2\)

_______a--------------->a_________(mol)

\(2Al+3Cl_2\underrightarrow{t^o}2AlCl_3\)

_b----------------->b______________(mol)

\(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)

_c------------------>c______________(mol)

=> 95a + 133,5b + 162,5 = 39,1 (3)

(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,1\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\) 

=> m = 24.0,1 + 27.01 + 56.0,1 = 10,7(g)

b) \(\left\{{}\begin{matrix}m_{Mg}=24.0,1=2,4\left(g\right)\\m_{Al}=27.0,1=2,7\left(g\right)\\m_{Fe}=56.0,1=5,6\left(g\right)\end{matrix}\right.\)

nH2= 0,35(mol)

a) PTHH: Mg +  2 HCl -> MgCl2 + H2

x_________2x_______x______x(mol)

PTHH: Fe + 2 HCl -> FeCl2 + H2

y________2y________y_____y(mol)

Ta có hpt: \(\left\{{}\begin{matrix}24x+56y=13,2\\x+y=0,35\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,15\end{matrix}\right.\)

b) m=m(muối khan)= mMgCl2 + mFeCl2= 95.x+127y=95.0,2+127.0,15= 38,05(g)

a)

Gọi 

\(n_{Fe} = a(mol) ; n_{Mg} = b(mol)\\ \Rightarrow 56a + 24b = 13,2(1)\)

\(Mg + 2HCl \to MgCl_2 + H_2\\ Fe + 2HCl \to FeCl_2 + H_2\)

Theo PTHH : \(n_{H_2} = a + b = 0,35(mol)\)(2)

Từ (1)(2) suy ra a = 0,15 ;b = 0,2

Vậy : 

\(\%m_{Fe} = \dfrac{0,15.56}{13,2}.100\% = 63,64\%\\ \Rightarrow m_{Mg} = 100\% - 63,64\% = 36,36\%\)

b)

Ta có :\(n_{HCl} = 2n_{H_2} = 0,7(mol)\)

Bảo toàn khối lượng :

\(m_{muối} = m_{kim\ loại} + m_{HCl} - m_{H_2} = 13,2 + 0,7.36,5 - 0,35.2=38,05(gam)\)

Sửa đề: đktc → đkc

a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: 24n_Mg + 56n_Fe = 13,2 (1)

\(n_{H_2}=\dfrac{8,6765}{24,79}=0,35\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Mg}+n_{Fe}=0,35\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,2\left(mol\right)\\n_{Fe}=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,2.24}{13,2}.100\%\approx36,36\%\\\%m_{Fe}\approx63,64\%\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\n_{FeCl_2}=n_{Fe}=0,15\left(mol\right)\end{matrix}\right.\)

⇒ m _{muối khan} = 0,2.95 + 0,15.127 = 38,05 (g)

a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{FeCl_2}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)

b, \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,15}=4\left(M\right)\)

c, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)

Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,6\left(mol\right)\)

\(\Rightarrow V_{NaOH}=\dfrac{0,6}{1}=0,6\left(l\right)=600\left(ml\right)\)

\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe,pư}=n_{FeCl_2}=n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ m_{Fe,pư}=0,3.56=16,8g\\ b.n_{HCl}=0,3.2=0,6mol\\ C_{M_{HCl}}=\dfrac{0,6}{0,15}=4M\\ c.2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\\ n_{NaOH}=0,3.2=0,6mol\\ V_{ddNaOH}=\dfrac{0,6}{1}=0,6l=600ml\)

a. ptpư:

Fe     +     S    →   FeS
0,2 <----- 0,2 <------ 0,2

FeS + 2HCl → FeCl₂ + H₂S
0,2 <-------------------------- 0,2

Fe + 2HCl → FeCl₂ + H₂
0,1 <----------------------- 0,1

H₂S + 2NaOH → Na₂S + 2H₂O

b.

nH₂ = 2,24/22,4 = 0,1 mol

nH₂S = 6,72/22,4 – 0,1 = 0,2 mol

nFe = 0,3 mol; nS =0,2

mX = (0,2+0,1).56 + 0,2.32 = 23,3 gam

\(a)n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ n_{Mg}=\dfrac{4,8}{24}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1       0,2            0,1         0,1

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

0,2        0,4           0,2            0,2

\(V_{H_2}=\left(0,1+0,2\right).22,4=6,72l\\ b)V_{ddHCl}=\dfrac{0,2+0,4}{2}=0,3l\\ c)m_{muối}=0,1.127+95.0,2=31,7g\)