Theo đề gọi \(\left\{{}\begin{matrix}n_{Fe_2O_3}=3x\left(mol\right)\\n_{CuO}=2x\left(mol\right)\end{matrix}\right.\)

Có: \(m_{hh}=m_{Fe_2O_3}+m_{CuO}=160.3x+80.2x=32\)

\(\Rightarrow x=0,05\\ \Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,05.3=0,15\left(mol\right)\\n_{CuO}=0,05.2=0,1\left(mol\right)\end{matrix}\right.\)

\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)

0,15 ---->0,45-->0,3

\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

0,1 --->0,1-->0,1

a. \(m_{kim.loại}=m_{Fe}+m_{Cu}=0,3.56+0,1.64=23,2\left(g\right)\)

b. \(V_{H_2}=\left(0,45+0,1\right).22,4=12,32\left(l\right)\)

\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{Fe}=a\left(mol\right);n_{Cu}=0,5a\left(mol\right)\\ m_{hhB}=17,6\\ \Leftrightarrow56a+64.0,5a=17,6\\ \Leftrightarrow a=0,2\left(mol\right)\\ \Rightarrow n_{Fe}=0,2\left(mol\right);n_{Cu}=0,1\left(mol\right)\\ a,n_{H_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,2+0,1=0,4\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\\ b,Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ Vì:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ \Rightarrow ddC:FeCl_2,HCldư\\ n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeCl_2}=0,2.127=25,4\left(g\right)\\ n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\)

\(\Rightarrow m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)

\(a.Đặt:n_{Mg}=3x\left(mol\right)\Rightarrow n_{Fe}=x\left(mol\right)\\ \Rightarrow m_{hh}=3x.24+x.56=19,2\\ \Rightarrow x=0,15\left(mol\right)\\ \Rightarrow m_{Mg}=0,15.3.24=10,8\left(g\right);m_{Fe}=0,15.56=8,4\left(g\right)\\ b.Mg+2HCl\rightarrow MgCl_2+H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow n_{H_2}=n_{Mg}+n_{Fe}=0,45+0,15=0,6\left(mol\right)\\ \Rightarrow V_{H_2}=0,6.22,4=13,44\left(l\right)\)

\(\left\{{}\begin{matrix}CuO:a\\Fe2O3:2a\end{matrix}\right.\)

a.\(80a+320a=24\Leftrightarrow a=0.06\)

\(\Rightarrow\left\{{}\begin{matrix}CuO=0.06\\Fe2O3=0.12\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}CuO=4.8g\\Fe2O3=19.2g\end{matrix}\right.\)

b.\(CuO+H2\rightarrow Cu+H2O\)

    a           a         a

\(Fe2O3+3H2\rightarrow2Fe+3H2O\)

    2a          6a       4a

\(\Rightarrow V_{H2}=\left(a+6a\right)\times22.4=9.408l\)

c.nHCl = 0.2 mol

\(Fe+2HCl\rightarrow FeCl2+H2\)

 0.1     0.2

m chất rắn còn lại = mCu + m Fe ban đầu - m Fe bị hòa tan

                             = \(a\times64+4a\times56-0.1\times56=11.68g\)

Tính %m mỗi oxit chứ:v

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{Fe_3O_4}=x\left(mol\right)\\n_{ZnO}=y\left(mol\right)\end{matrix}\right.\)

\(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)

 x --------> 4x ---> 3x

\(ZnO+H_2\underrightarrow{t^o}Zn+H_2O\)

y ------> y --> y

Có hệ phương trình \(\left\{{}\begin{matrix}232x+81y=19,7\\4x+y=0,3\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,05\\y=0,1\end{matrix}\right.\)

\(\%_{m_{Fe_3O_4}}=\dfrac{232.0,05.100}{19,7}=58,88\%\)

\(\%_{m_{ZnO}}=\dfrac{81.0,1.100}{19,7}=41,12\%\)

\(n_{Fe}=3x=3.0,05=0,15\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\\ n_{Zn}=y=0,1\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)

a) Gọi số mol H₂ là x

=> nH2O=x(mol)

Theo ĐLBTKL: mA+mH2=mB+mH2O

=> 200 + 2x = 156 + 18x

=> x = 2,75 (mol)

=> VH2=2,75.22,4=61,6(l)

b) Gọi nCuO=a(mol)

nFe2O3=1,5a(mol)

=> 80a + 240a + 102b = 200

=> 320a + 102b = 200

PTHH: CuO + H₂ --t^o--> Cu + H₂O

              a---------------->a

            Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

             1,5a------------------>3a

=> 64a + 168a + 102b = 156

=> 232a + 102b = 156

=> a = 0,5; b = \(\dfrac{20}{15}\)

%mCuO=\(\dfrac{0,5.80}{200}\).100%=20%

%mFe2O3=\(\dfrac{0,75.160}{200}\).100%=60%

%mAl2O3=\(\dfrac{\dfrac{20}{15}102}{200}\).100%=20%

c) nH2=\(\dfrac{2,75}{5}\)=0,55(mol)

nFeO(tt)=\(\dfrac{36}{72}\)=0,5(mol)

Gọi số mol FeO phản ứng là t (mol)

PTHH: FeO + H₂ --t^o--> Fe + H₂O

              t--------------->t

=> 56t + (0,5-t).72 = 29,6

=> t = 0,4 (mol)

=> H%=\(\dfrac{0,4}{0,5}\).100%=80%

tỉ leejlaf 1:1,5 chứ

4) x,y lần lượt là số mol của M và M2O3
=> nOxi=3y=nCO2=0,3 => y=0,1
Đề cho x=y=0,1 =>0,1M+0,1(2M+48)=21,6 =>M=56 => Fe và Fe2O3
=> m=0,1.56 + 0,1.2.56=16,8

2)X + 2HCl === XCl2 + H2
n_h2 = 0,4 => X = 9,6/0,4 = 24 (Mg)
=>V_HCl = 0,4.2/1 = 0,8 l

3) n_H2O = 0,8 => n_H2 = 0,8 => v = 0,8.22,4 = 17,92 l

áp dụng đl bảo toàn khối lượng

=> 47,2 + 0,8.2 = m + 14,4

=> m = 34,4 (g)