Na₂SO₄ + BaCl₂ 2NaCl + BaSO₄

n_Na2SO4=0,05.0,1=0,005(mol)

n_BaCl2=0,1.0,1=0,01(mol)

Vì 0,005<0,01 nên BaCl₂ dư 0,005(mol)

Theo PTHH ta có;

n_Na2SO4=n_BaSO4=0,005(mol)

2n_Na2SO4=n_NaCl=0,01(mol)

m_BaSO4=0,005.233=1,165(g)

C_M dd BaCl₂=\(\dfrac{0,01}{0,15}=115\)M

PTHH: \(Na_2SO_4+CaCl_2\rightarrow2NaCl+CaSO_4\downarrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Na_2SO_4}=0,1\cdot0,5=0,05\left(mol\right)\\n_{CaCl_2}=0,1\cdot0,4=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Na₂SO₄ dư

\(\Rightarrow\left\{{}\begin{matrix}n_{CaSO_4}=0,04\left(mol\right)\\n_{NaCl}=0,08\left(mol\right)\\n_{Na_2SO_4\left(dư\right)}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_4}=0,04\cdot136=5,44\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,08}{0,1+0,1}=0,4\left(M\right)\\C_{M_{Na_2SO_4\left(dư\right)}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)

\(a,n_{Na_2CO_3}=\dfrac{106.10}{100.106}=0,1mol\\ BaCl_2+Na_2CO_3\rightarrow BaCO_3+2NaCl\\ n_{BaCO_3}=n_{Na_2CO_3}=0,1mol\\ m_A=m_{BaCO_3}=0,1.197=19,7g\\ b,n_{NaCl}=0,1.2=0,2mol\\ C_{\%B}=C_{\%NaCl}=\dfrac{0,2.58,5}{100+106-19,7}\cdot100=6,28\%\\ c.BaCO_3\xrightarrow[]{t^0}BaO+CO_2\\ n_{CO_2}=n_{BaCO_3}=0,1mol\\ n_{Ca\left(OH\right)_2}=0,08.1=0,08mol\\ T=\dfrac{0,08}{0,1}=0,8\\ \Rightarrow0,5< T< 1\)

Pứ tạo 2 muối

\(n_{CaCO_3}=a,n_{Ca\left(HCO_3\right)_2}=b\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2\\ \Rightarrow\left\{{}\begin{matrix}a+b=0,08\\a+2b=0,1\end{matrix}\right.\\ \Rightarrow a=0,06;b=0,02\\ m_{muối}=0,06.100+0,02.162=9,24g\)

\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ ..........0,15.......0,15.......0,15.......0,15\left(mol\right)\)

\(m_{Zn}=65\cdot0,15=9,75\left(g\right)\)

\(b,m_{H_2SO_4}=98\cdot0,15=14,7\left(mol\right)\\ c,m_{dd_{H_2SO_4}}=\dfrac{14,7\cdot100}{20}=\dfrac{147}{2}\left(g\right)\\ d,C\%_{dd_{ZnSO_4}}=\dfrac{0,15\cdot161}{\dfrac{147}{2}}\cdot100\approx32,86\%\)

Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\)

a. PTHH: \(Ba\left(OH\right)_2+Na_2SO_4--->BaSO_4\downarrow+2NaOH\)

b. Theo PT: \(n_{BaSO_4}=n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\)

=> \(m_{BaSO_4}=0,2.233=46,6\left(g\right)\)

c. Theo PT: \(n_{Na_2SO_4}=n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\)

=> \(m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)

=> \(C_{\%_{Na_2SO_4}}=\dfrac{28,4}{240}.100\%=11,83\%\)