Câu B chịu nka~~

→nH2O(dd bđ)=1120−190,418=51,6(mol)→nH2O(dd bđ)=1120−190,418=51,6(mol)

$S{}^{}+{}^{}O\to {}^{}S{}^{}$

$\to S{}^{}$ hết, ${}^{}O$ dư

nH2

PTHH: \(SO_3+H_2O\rightarrow H_2SO_4\)

Ta có: \(n_{SO_3}=\dfrac{200}{80}=2,5\left(mol\right)=n_{H_2SO_4}\)

Mặt khác: \(m_{ddH_2SO_4}=1000\cdot1,12=1120\left(g\right)\) \(\Rightarrow m_{H_2SO_4\left(ban.đầu\right)}=1120\cdot17\%=190,4\left(g\right)\)

Bảo toàn khối lượng: \(m_{ddH_2SO_4\left(sau\right)}=m_{SO_3}+m_{ddH_2SO_4\left(ban.đầu\right)}=1320\left(g\right)\)

\(\Rightarrow C\%=\dfrac{2,5\cdot98+190,4}{1320}\cdot100\%\approx32,98\%\)

\(n_{SO_3}=\dfrac{200}{80}=2.5\left(mol\right)\)

\(m_{dd_{H_2SO_4}}=1000\cdot1.12=1120\left(g\right)\)

\(m_{H_2SO_4}=1120\cdot17\%=190.4\left(g\right)\)

\(SO_3+H_2O\rightarrow H_2SO_4\)

\(2.5.....................2.5\)

\(m_{H_2SO_4}=2.5\cdot98+190.4=435.4\left(g\right)\)

\(m_{dd_{H_2SO_4}}=200+1120=1320\left(g\right)\)

\(C\%_{H_2SO_4}=\dfrac{435.4}{1320}\cdot100\%=33\%\)

$SO_3 + H_2O \to H_2SO_4$
$n_{H_2SO_4} = n_{SO_3} = \dfrac{200}{80} = 2,5(mol)$
$m_{dd\ H_2SO_4\ 17\%} =1000.1,12 = 1120(gam)$

Sau khi pha : 

$m_{dd} = 200 + 1120 = 1320(gam)$
$m_{H_2SO_4} = 1120.17\% + 2,5.98 = 435,4(gam)$
$C\%_{H_2SO_4} = \dfrac{435,4}{1320}.100\% = 33\%$

n_K = 39/400.100%=9,75%

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giup mk voi

\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)

C%NaOH=\(\dfrac{20}{200}100\)=10%

2 

mNaCl= 34g

=>C%NaCl=\(\dfrac{34}{200}.100\)=17%

3

m KOH=20g

=>C%=\(\dfrac{35}{15+200}\)=16,279%

4

C%KCl=\(\dfrac{25}{275}100\)=9,09%

H2SO4 + nSO3 => H2SO4.nSO3

H2SO4.nSO3 + nH2O >> n+1H2SO4

H2SO4 + 2NaOH >> Na2SO4 + 2H2O

Số mol NaOH = 0,008 , số mol H2SO4 200ml = 0,008/2 . 200/10 =0,08
Theo (2) nH2SO4.nSO3 =0,08/n+1

MH2SO4.nSO3 =98 +80n = 6,76/0,08/n+1 =84,5n+ 84,5
13,5 =4,5n
=>n=3

%SO3=3.80/2.80+98 =71%

c,Theo câu b , hàm lượng % của SO3 có trong oleum trên là 71

Cứ 100g oleum có 71g SO3 và 29g H2SO4 Khi đó mdd = 1,31.100 = 131g
a g có 71a/100 ...............29a/100

Vì dd H2SO4 có C=40%
Cứ 100g dd có 40g H2SO4 và 60g H2O
=>131g >> 131.40/100 = 52,4g H2SO4 và 131.60/100 = 78,6 g H2O

Khi cho oleum vào dd H2SO4 thì SO3+H2O

SO3 + H2O >> H2SO4
Cứ 80g cần 18g >> 98g
Vậy ..x..g cần 78,6g >>..y..g

x= 78,6.80/18 = 349,3g
y= 78,6.98/18 = 427,9g

Trong loại oleum mới 10% thì mSO3 = 71a/100 -349,3g

và mH2SO4 = 29a/100 +52,4+ 427,9

=> 71a/100 -349,4 / 29a/100 +480,3 = 10/90

=> Bạn ấn máy tìm a nhé

a)

\(SO_3 + H_2O \to H_2SO_4\)

Theo PTHH : \(n_{H_2SO_4} = n_{SO_2} = \dfrac{8}{80} = 0,1(mol)\)

\(\Rightarrow C\%_{H_2SO_4} = \dfrac{0,1.98}{200}.100\% = 4,9\%\)

b)

\(2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O\)

Theo PTHH : \(n_{NaOH} = 2n_{H_2SO_4} = 0,2(mol)\\ \Rightarrow m_{dd\ NaOH} = \dfrac{0,2.40}{4\%} = 200(gam)\)

\(a,PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\\ \Rightarrow m_{CuSO_4}=0,1\cdot160=16\left(g\right)\\ b,n_{H_2SO_4}=n_{CuO}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{H_2SO_4}}=0,1\cdot98=9,8\left(g\right)\\ \Rightarrow C\%_{H_2SO_4}=\dfrac{9,8}{200}\cdot100\%=4,9\%\)