\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ FeO+H_2SO_4\rightarrow FeSO_4+H_2O\\ n_{Zn}=n_{H_2}=0,2mol\\ \%m_{Zn}=\dfrac{0,2.65}{20}\cdot100\%=65\%\\ \%m_{Fe}=100\%-65\%=35\%\)

a, Ta có: 27n_Al + 56n_Fe = 27,8 (1)

PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Fe}=0,4\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%\approx19,42\%\\\%m_{Fe}\approx80,58\%\end{matrix}\right.\)

b, \(n_{H_2SO_4}=n_{H_2}=0,7\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,7}{0,5}=1,4\left(M\right)\)

n_H2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Fe + 2HCl ---> FeCl₂ + H₂

0,15    0,3           0,15     0,15

m_Fe = 0,15.56 = 8,4 (g)

m_Fe2O3 = 24,4 - 8,4 = 16 (g)

n_Fe2O3 = \(\dfrac{16}{160}=0,1\left(mol\right)\)

%m_Fe = \(\dfrac{8,4}{24,4}=34,42\%\)

%m_Fe2O3 = \(100\%-34,42\%=65,58\%\)

Fe₂O₃ + 6HCl ---> 2FeCl₃ + 3H₂O

0,1            0,6          0,2           0,3

n_{HCl (ban đầu)} = 0,8.1,5 = 1,2 (mol)

n_{HCl (dư)} = 1,2 - 0,3 - 0,6 = 0,3 (mol)

=> \(\left\{{}\begin{matrix}C_{MFeCl_3}=\dfrac{0,2+0,15}{0,8}=0,4375M\\C_{MHCl\left(dư\right)}=\dfrac{0,3}{0,8}=0,375M\end{matrix}\right.\)

PTHH: 

FeCl₃ + 3NaOH ---> Fe(OH)₃ + 3NaCl

0,35        1,05

HCl + NaOH ---> NaCl + H₂O

0,3       0,3

=> \(V_{ddNaOH}=\dfrac{1,05+0,3}{1}=1,35\left(l\right)=1350\left(ml\right)\)

a) Đặt \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow24a+27b=5,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Bảo toàn electron: \(2a+3b=0,5\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%\approx47,06\%\\\%m_{Al}=52,94\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,5\cdot36,5}{7,3\%}=250\left(g\right)\)

\(\Rightarrow V_{HCl}=\dfrac{250}{1,2}\approx208,33\left(ml\right)\)

Gọi \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo pt: \(\Rightarrow\left\{{}\begin{matrix}3x+y=0,2\\27x+56y=5,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=\dfrac{19}{470}\\y=\dfrac{37}{470}\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{5,5}\cdot100\%=19,84\%\)

\(\%m_{Fe}=100\%-19,84\%=80,16\%\)

Coi X gồm Fe và O.

Ta có: 56n_Fe + 16n_O = 49,6 (1)

\(n_{SO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

BT e, có: 3n_Fe - 2n_O = 2n_SO2 = 0,8 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=0,7\left(mol\right)\\n_O=0,65\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\%m_O=\dfrac{0,65.16}{49,6}.100\%\approx20,97\%\)

Muối thu được là Fe₂(SO₄)₃

BTNT Fe, có: \(n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Fe}=0,35\left(mol\right)\)

\(\Rightarrow m_{Fe_2\left(SO_4\right)_3}=0,35.400=140\left(g\right)\)

Chọn A