Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\end{matrix}\right.\)

PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)

                    0,2_____0,4_____0,2____0,2_____0,2  (mol)

            \(CaO+2HCl\rightarrow CaCl_2+H_2O\)

                 0,1_____0,2_____0,1____0,1    (mol)

Ta có: \(\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CaO}=\dfrac{5,6}{5,6+20}\cdot100\%=21,875\%\\\%m_{CaCO_3}=78,125\%\end{matrix}\right.\)

Mặt khác: \(m_{CO_2}=0,2\cdot44=8,8\left(g\right)\)

\(\Rightarrow m_{dd\left(sau.p/ứ\right)}=m_{CaO}+m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=66,8\left(g\right)\)

\(\Rightarrow C\%_{CaCl_2}=\dfrac{33,3}{66,8}\cdot100\%\approx49,85\%\)

nCO2=\(\dfrac{4,48}{22,4}=0,2\) mol

nCaCl₂=\(\dfrac{33,3}{111}=0,3\)

CaCO₂ + 2HCl → CaCl₂ + CO₂ + H₂O

  0,2           ←         0,2    ← 0,2

CaO + 2HCl  → CaCl₂ + H₂O     

 0,1              ←    0,1

a)  % CaO=\(\dfrac{0,1.56}{0,1.56+0,2.100}.100\%=21,875\%\)    

   % CaCO₃ =100% - 21,875%= 78,125%

b) a = mCaO+mCaCO₃ =0,1.56+0,2.100=25,6g

mdd sau pư= a + mddHCl - mCO2

                  = 25,6 + 50 - 0,2.44=66,8g

C%CaCl₂=\(\dfrac{33,3}{66,8}.100\%\simeq49,85\%\)

PTHH: \(CaO+2HCl\rightarrow CaCl_2+H_2O\)  (1)

            \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)  (2)

a) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{CaO}=0,1mol\\n_{CaCO_3}=0,2mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{hh}=20+5,6=25,6\left(g\right)\)

b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=0,2mol\\n_{HCl\left(2\right)}=0,4mol\end{matrix}\right.\)

\(\Rightarrow\Sigma n_{HCl}=0,6mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,3}=2\left(M\right)\)

PT: \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)

\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\) (2)

a, Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(\Sigma n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\)

Theo PT (2): \(n_{CaCl_2}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow n_{CaCl_2\left(1\right)}=0,3-0,2=0,1\left(mol\right)\)

Theo PT (1): \(n_{CaO}=n_{CaCl_2}=0,1\left(mol\right)\)

Theo PT (2): \(n_{CaCO_3}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow m_A=m_{CaO}+m_{CaCO_3}=0,1.56+0,2.100=25,6\left(g\right)\)

b, Theo PT (1) + (2): \(\Sigma n_{HCl}=2n_{CaO}+2n_{CaCO_3}=0,6\left(mol\right)\)

\(\Rightarrow C_{M_{ddHCl}}=\dfrac{0,6}{0,3}=2M\)

Bạn tham khảo nhé!

Đáp án C

Chọn đáp án A.

\(PTHH:CaO+2HCl\rightarrow CaCl2+H2O\)

________0,1____________0,1____________

\(CaCO3+2HCl\rightarrow CaCl2+CO2+H2O\)

0,2_____________0,2_________0,2_________

Ta có :

\(n_{CO2}=\frac{4,48}{22,4}=0,2\left(mol\right)\)

\(n_{CaCl2}=\frac{33,3}{111}=0,3\left(mol\right)\)

\(\rightarrow n_{CaCO3}=0,2\left(mol\right),n_{CaO}=0,1\left(mol\right)\)

\(a=m_{CaCO3}+m_{CaO}=0,2.100+0,1.56=25,6\left(g\right)\)

nCaCl2 = 0.3 mol

nCO2 = 0.2 mol

CaCO3 + 2HCl => CaCl2 + CO2 + H2O

0.2_______0.4______0.2____0.2

CaO + 2HCl => CaCl2 + H2O

0.1_____0.2_____0.1

mA = mCaCO3 + mCaO = 0.2*100 + 0.1*56 = 25.6 g

CM HCl = 0.6/0.3 = 2M