PTHH: \(BaCl_2+H_2SO_4\rightarrow2HCl+BaSO_4\downarrow\) (1)
a) Ta có: \(\left\{{}\begin{matrix}m_{BaCl_2}=150\cdot5,2\%=7,8\left(g\right)\\m_{H_2SO_4}=250\cdot19,6\%=49\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=\frac{7,8}{208}=0,0375\left(mol\right)\\n_{H_2SO_4}=\frac{49}{98}=0,5\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\frac{0,0375}{1}< \frac{0,5}{1}\) \(\Rightarrow\) BaCl2 phản ứng hết, H2SO4 còn dư
\(\Rightarrow n_{BaSO_4}=0,0375mol\) \(\Rightarrow m_{BaSO_4}=0,0375\cdot233=8,7375\left(g\right)\)
b) Dung dịch A gồm: \(HCl\) và \(H_2SO_{4\left(dư\right)}\)
PTHH: \(HCl+NaOH\rightarrow NaCl+H_2O\) (2)
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\) (3)
Theo PTHH (1): \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{BaCl_2}=0,075mol=n_{HCl\left(2\right)}\\n_{H_2SO_4\left(dư\right)}=0,4625mol=n_{H_2SO_4\left(3\right)}\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH\left(2\right)}=0,075mol\\n_{NaOH\left(3\right)}=0,925mol\end{matrix}\right.\) \(\Rightarrow n_{NaOH}=1mol\)
\(\Rightarrow V_{NaOH}=\frac{1}{1,5}\approx0,67\left(l\right)=670\left(ml\right)\)