n\(_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,2 (mol)
\(\rightarrow m_{Zn}=0,2.65=13\left(g\right)\)
\(\Rightarrow m_{Cu,Ag}=45,5-13=32,5\left(g\right)\)
đặt số mol của Cu là a;Ag là b,ta có:
64a+108b=32,5(1)
\(Zn+\dfrac{1}{2}O_2\rightarrow ZnO\)
0,2 0,2 (mol)
\(\rightarrow m_{ZnO}=0,2.81=16,2\left(g\right)\)
\(\rightarrow m_{CuO,Ag_2O}=\)51,9-16,2=35,7(g)
\(Cu+\dfrac{1}{2}O_2\rightarrow CuO\)
a a (mol)
\(2Ag+\dfrac{1}{2}O_2\rightarrow Ag_2O\)
b \(\dfrac{1}{2}b\) (mol)
ta có:\(80a+116b=35,7\)(2)
từ (1) và (2) ta có hệ:
\(\Leftrightarrow\left\{{}\begin{matrix}64a+108b=32,5\\80a+116b=35,7\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=\dfrac{107}{1520}\\b=\dfrac{197}{760}\end{matrix}\right.\)
\(\rightarrow m_{Cu}=\dfrac{107}{1520}.64\approx4,5\left(g\right)\)
\(m_{Ag}=\dfrac{197}{760}.108\approx28\left(g\right)\)
