(+) khi \(A\) tác dụng với dung dịch \(HCl\)
\(ptpư:\dfrac{Zn}{x}\dfrac{+}{ }\dfrac{2HCl}{ }\dfrac{\rightarrow}{ }\dfrac{ZnCl_2}{ }\dfrac{+}{ }\dfrac{H_2}{x}\)
\(ptpư:\dfrac{2Ag}{y}\dfrac{+}{ }\dfrac{2HCl}{ }\dfrac{\rightarrow}{ }\dfrac{2AgCl}{ }\dfrac{+}{ }\dfrac{H_2}{0,5y}\)
\(\Rightarrow x+0,5y=0,2\) (1)
(+) khi \(A\) tác dụng với dung dịch \(H_2SO_4\) đặc nóng
\(ptpư:\dfrac{Zn}{x}\dfrac{+}{ }\dfrac{2H_2SO_4}{ }\dfrac{\rightarrow}{ }\dfrac{ZnSO_4}{ }\dfrac{+}{ }\dfrac{SO_2}{x}\dfrac{+}{ }\dfrac{2H_2O}{ }\)
\(ptpư:\dfrac{Ag}{y}\dfrac{+}{ }\dfrac{2H_2SO_4}{ }\dfrac{\rightarrow}{ }\dfrac{Ag_2SO_4}{ }\dfrac{+}{ }\dfrac{SO_2}{y}\dfrac{+}{ }\dfrac{2H_2O}{ }\)\(\Rightarrow x+y=0,3\) (2)
từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x+0,5y=0,2\\x+y=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\Rightarrow m=65.0,1+108.0,2=28,1\left(g\right)\)