\(2n_{Cu}=3n_{NO}+n_{NO_2}\)
\(\Rightarrow3n_{NO}+n_{NO_2}=0,4\)
\(n_{NO}+n_{NO_2}=0,28\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NO}=0,06\left(mol\right)\\n_{NO_2}=0,22\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{Cu^{2+}}=n_{Cu\left(NO_3\right)_2}=0,2\left(mol\right)\)
\(\Rightarrow n_{NO_3^-}=2n_{Cu\left(NO_3\right)_2}=0,4\left(mol\right)\)
\(\Rightarrow n_{NO_3^-}=n_{HNO_3}=n_{NO}+n_{NO_2}+n_{NO_3^-}=0,68\left(mol\right)\)
\(\Rightarrow C_{MHNO_3}=\frac{0,68}{0,2}=3,4\left(M\right)\)