Câu 3:
a) Gọi số mol Al, Fe là a, b (mol)
=> 27a + 56b = 1,1 (1)
\(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a---------------->1,5a
Fe + H2SO4 --> FeSO4 + H2
b---->b---------------->b
=> 1,5a + b = 0,04 (2)
(1)(2) => a = 0,02 (mol); b = 0,01 (mol)
\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,02.27}{1,1}.100\%=49,1\%\\\%m_{Fe}=\dfrac{0,01.56}{1,1}.100\%=50,9\%\end{matrix}\right.\)
b) \(m_{H_2SO_4\left(lý.thuyết\right)}=\left(1,5a+b\right).98=3,92\left(g\right)\)
=> \(m_{H_2SO_4\left(tt\right)}=\dfrac{3,92.120}{100}=4,704\left(g\right)\)
=> \(C\%=\dfrac{4,704}{49}.100\%=9,6\%\)
c) \(\left\{{}\begin{matrix}n_{Al}=\dfrac{0,66.49,1\%}{27}=0,012\left(mol\right)\\n_{Fe}=\dfrac{0,66.50,9\%}{56}=0,006\left(mol\right)\end{matrix}\right.\)
PTHH: 2Al + 6H2SO4 --> Al2(SO4)3 + 3SO2 + 6H2O
0,012------------------------->0,018
2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
0,006------------------------->0,009
=> VSO2 = (0,018 + 0,009).22,4 = 0,6048 (l)