\(n_{FeCl_2}=\dfrac{25.4}{127}=0.2\left(mol\right)\)
\(n_{H_2O}=\dfrac{5.4}{18}=0.3\left(mol\right)\)
\(Fe_xO_y+yH_2\underrightarrow{t^0}xFe+yH_2O\)
...........................\(x\) ..........\(y\)
...........................\(0.2\) ......\(0.3\)
\(\Rightarrow0.3x=0.2y\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{0.2}{0.3}=\dfrac{2}{3}\)
\(CT:Fe_2O_3\)
\(m_{Fe_2O_3}=0.2\cdot2\cdot160=64\left(g\right)\)