PTHH: 4P + 5O2 \(\underrightarrow{t^o}\) 2P2O5 (1)
P2O5 + 3H2O \(\rightarrow\) 2H3PO4 (2)
nP = \(\frac{12,4}{31}=0,4\left(mol\right)\)
Theo PT(1): n\(O_2\) = \(\frac{5}{4}\)nP = \(\frac{5}{4}\).0,4 = 0,5 (mol)
=> V\(O_2\) cần dùng = 0,5.22,4 = 11,2 (l)
b) Theo PT(1): n\(P_2O_5\) = \(\frac{2}{4}n_P=\frac{1}{2}.0,4=0,2\left(mol\right)\)= n \(P_2O_5\)(2)
Theo PT(2): n\(H_3PO_4\) = 2n\(P_2O_5\) = 2.0,2 = 0,4 (mol)
=> m\(H_3PO_4\) = 0,4.98 = 39,2 (g)
=> C%dd tạo thành = \(\frac{m_{ct}}{m_d_d}.100\%=\frac{39,2}{200}.100\%=19,6\%\)
+PTHH:
4P + 5O2 => 2P2O5
P2O5 + 3H2O => 2H3PO4
nP = m/M = 12.4/31 = 0.4 (mol)
===> nO2 = 0.5 (mol)
===> VO2 = 22.4 x 0.5 = 11.2 (l)
Ta có: nP2O5 = 0.2 (mol)
===> nH3PO4 = 0.4 (mol)
===> mH3PO4 = n.M = 0.4 x 98 = 39.2 (g)
C%ddH3PO4 = 39.2 x 100/200 = 19.6 (%)
nP= 0.4 mol
4P + 5O2 -to-> 2P2O5
0.4__0.5_______0.2
VO2= 0.5*22.4=11.2l
P2O5 + 3H2O --> 2H3PO4
0.2______________0.4
mdd sau phản ứng= mP2O5 + mH2O= 0.2*142+200=228.4g
mH3PO4= 0.4*98=39.2g
C%H3PO4= 39.2/228.4*100%= 17.16%