a)
Gọi số mol Fe, Zn là a, b (mol)
=> 56a + 65b = 8,2 (1)
PTHH: \(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)
a--------------->a
\(Zn+Cl_2\underrightarrow{t^o}ZnCl_2\)
b------------->b
=> 162,5a + 136b = 21,69 (2)
(1)(2) => a = 0,1 (mol); b = 0,04 (mol)
\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1.56}{8,2}.100\%=68,3\%\\\%m_{Zn}=\dfrac{0,04.65}{8,2}.100\%=31,7\%\end{matrix}\right.\)
b)
Ta có: \(\dfrac{n_{Fe}}{n_{Zn}}=\dfrac{0,1}{0,04}=2,5\)
Mà nFe + nZn = 0,07
=> nFe = 0,05 (mol); nZn = 0,02 (mol)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,05--------------------->0,05
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,02----------------------->0,02
=> V = (0,05 + 0,02).22,4 = 1,568 (l)