\(n_{Fe}=x;n_{Zn}=y\\ PTHH:2Fe+6H_2SO_4\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+6H_2O+3SO_2\\ PTHH:Zn+2H_2SO_4\underrightarrow{t^o}ZnSO_4+2H_2O+SO_2\\ hpt:\left\{{}\begin{matrix}56x+65y=72,6\\22,4\left(1,5x+y\right)=33,6\end{matrix}\right.\Leftrightarrow x=y=0,6\\ \rightarrow\left\{{}\begin{matrix}m_{Fe}=0,6.56=33,6\left(g\right)\\m_{Zn}=0,6.65=39\left(g\right)\end{matrix}\right.\\ n_{H_2SO_4}=3x+2y=3\left(mol\right)\\ PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ \rightarrow V_{NaOH}=\frac{3.2}{0,5}=12\left(l\right)\)
a) 2Fe + 6H2SO4 --> Fe2(SO4)3 + 6H2O + 3SO2
x ------------3x------------------------------------------------ 3/2x
Zn + 2H2SO4 --> ZnSO4 + 2H2O + SO2
y ------------2y--------------------------------------- y
nSO2 = 33,6:22,4 = 1,5 mol
=> 3/2x +y = 1,5 và 56x + 65y = 72,6
<=> x = 0,6 và y = 0,6
=> mFe = 56.0,6 = 33,6 g
mZn = 65.0,6 = 39 g
b) nH2SO4=3x+2y=3 mol
2NaOH + H2SO4 = Na2SO4 + 2H2O
6................3
nNaOH=6 mol -> V =6:0,5=12 l