\(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{Cl_2}=\dfrac{V_{Cl_2\left(ĐKTC\right)}}{22,4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:2Al+3Cl_2\rightarrow2AlCl_3\\ \dfrac{n_{Al}}{n_{Cl_2}}=\dfrac{1}{2}< \dfrac{2}{3}\Rightarrow Cl_2\text{ dư, bài toán tính theo }Al\\ \Rightarrow m_{AlCl_3}=n_{AlCl_3}\cdot M_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\)