PTHH: \(2KMnO_4+16HCl_{\left(đ\right)}\rightarrow2KCl+2MnCl_2+5Cl_2\uparrow+8H_2O\)
Ta có: \(n_{KMnO_4}=\dfrac{14,2}{158}=\dfrac{71}{790}\left(mol\right)\)
\(\Rightarrow n_{Cl_2}=\dfrac{71}{316}\left(mol\right)\) \(\Rightarrow V_{Cl_2}=\dfrac{71}{316}\cdot22,4\approx5,03\left(l\right)\)