\(a,Zn+2HCl\to ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2(mol);n_{HCl}=\dfrac{21,9}{36,5}=0,6(mol)\)
Vì \(\dfrac{n_{Zn}}{1}<\dfrac{n_{HCl}}{2}\) nên \(HCl\) dư
\(n_{HCl(dư)}=0,6-0,2.2=0,2(mol)\\ c,n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2(mol)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2(g)\\ V_{H_2}=0,2.22,4=4,48(l)\)