a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)

                 \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)

b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)

\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)

c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\) 

(Coi như thể tích dd thay đổi không đáng kể)

d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\) 

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)

a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

b. Đổi 100ml = 0,1 lít

Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)

Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)

=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)

c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)

=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)

a)

\(Fe + CuSO_4 \to FeSO_4 + Cu\)

Theo PTHH : 

\(n_{CuSO_4} = n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)\\ \Rightarrow V_{dd\ CuSO_4} = \dfrac{0,2}{0,1} = 2(lít)\)

b)

\(n_{CuSO_4} = 0,1.2,5 = 0,25(mol) > n_{Fe}= 0,2\) nên \(CuSO_4\) dư.

Ta có : 

\(n_{CuSO_4\ pư} = n_{FeSO_4} = n_{Fe} = 0,2(mol)\\ \Rightarrow n_{CuSO_4\ dư} = 0,25 - 0,2 = 0,05(mol)\)

Vậy : 

\(C_{M_{CuSO_4}} = \dfrac{0,05}{2,5} = 0,02M\\ C_{M_{FeSO_4}} = \dfrac{0,2}{2,5} = 0,08M\)

\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)

\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)

Bài 1. A gồm CuO và Cu dư.

dd X chứa CuSO₄.

Y là Cu. Khí C là SO₂.

dd D có K₂SO₃ và KOH dư.

\(a.A+2HCl\rightarrow ACl_2+H_2\\ ACl_2+2AgNO_3\rightarrow A\left(NO_3\right)_2+2AgCl\downarrow\\ n_{AgCl\downarrow}=\dfrac{57,4}{143,5}=0,4\left(mol\right)\\ n_A=n_{ACl_2}=\dfrac{n_{AgCl}}{2}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ b.M_A=\dfrac{13}{0,2}=65\left(\dfrac{g}{mol}\right)\\ \rightarrow A:Kẽm\left(Zn=65\right)\\ c.n_{HCl}=2.n_A=0,4\left(mol\right)\\ V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)=200\left(ml\right)\)