a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(1\right)\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,015\left(mol\right)\\n_{C_2H_2}=0,01\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{C_2H_4}=0,015.22,4=0,336\left(l\right)\\V_{C_2H_2}=0,01.22,4=0,224\left(l\right)\end{matrix}\right.\)

b, \(V_{ddBr_2}=\dfrac{0,035}{0,2}=0,175\left(l\right)\)

a, Ta có \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)

PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_4}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)

b, \(m_{CH_4}=0,05.16=0,8\left(g\right)\)

c, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,1}{1}=0,1\left(l\right)\)

\(m_{C_2H_4}=0,1.28=2,8\left(g\right)\)

 Ta có Cùng điều kiện -> Quy số lít về số mol.n(hh ban đầu) = 20 mol; n(hh sau) = 16 lít

=> H2 phản ứng mất 4 lít => C2H2 có 2 lít và CH4 có 8 lít

a.\(n_{hh}=\dfrac{V_{hh}}{22,4}=\dfrac{0,896}{22,4}=0,04mol\)

\(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{8}{160}=0,05mol\)

Gọi \(n_{C_2H_2}\) là x => \(V_{C_2H_2}=22,4x\)

       \(n_{C_2H_4}\) là y => \(V_{C_2H_4}=22,4y\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

  x           2x                 x         ( mol )

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

   y         y                y            ( mol )

Ta có hpt:

\(\left\{{}\begin{matrix}22,4x+22,4y=0,896\\2x+y=0,05\end{matrix}\right.\)   \(\Leftrightarrow\left\{{}\begin{matrix}x=0,01\\y=0,03\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{C_2H_2}=0,01.22,4=0,224\\V_{C_2H_4}=0,03.22,4=0,672\end{matrix}\right.\)

\(\%V_{C_2H_2}=\dfrac{0,224}{0,896}.100=25\%\)

\(\%V_{C_2H_4}=100-25=75\%\)

b.\(m_{Sp}=0,01.186+0,03.346+0,03.188=16,02g\)

( Em cảm ơn anh Kudo Sinichi rất nhiều ạ!! )

\(V_{khí.giảm}=V_{C_2H_2}\)

\(\%C_2H_2=\dfrac{4,48}{6,72}.100=66,67\%\)

\(\%CH_4=100\%-66,67\%=33,33\%\)

\(\left\{{}\begin{matrix}CH_4:x\left(mol\right)\\C_2H_2:y\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}16x+26y=11,6\\x+y=\dfrac{11,2}{22,4}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,14mol\\y=0,36mol\end{matrix}\right.\)

a)\(\%V_{CH_4}=\dfrac{0,14}{0,5}\cdot100\%=28\%\)

\(\%V_{C_2H_2}=100\%-28\%=72\%\)

\(\%m_{CH_4}=\dfrac{0,14\cdot16}{11,6}\cdot100\%=19,31\%\)

\(\%m_{C_2H_2}=100\%-19,31\%=80,69\%\)

b)\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)

Dẫn dung dịch qua bình đựng brom chỉ có \(C_2H_2\) tác dụng.

\(\Rightarrow m_{tăng}=m_{C_2H_2}=0,25\cdot26=6,5g\)

Khí thoát ra ngoài : $CH_4$

$C_2H_2 + 2Br_2 \to C_2H_2Br_4$

$V_{CH_4} = 1,12(lít) \Rightarrow \%V_{CH_4} = \dfrac{1,12}{3,36}.100\% = 33,33\%$
$\%V_{C_2H_2} = 100\% -33,33\% = 66,67\%$

Ta có: \(n_{Br_2}=\dfrac{48}{160}=0,3\left(mol\right)\)

PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

____0,15___0,3 (mol)

\(\Rightarrow\left\{{}\begin{matrix}V_{C_2H_2}=0,15.22,4=3,36\left(l\right)\\V_{CH_4}=2,24\left(l\right)\end{matrix}\right.\)

Bạn tham khảo nhé!

$C_2H_2+2Br_2\to Br_2CH-CHBr_2$

$n_{Br_2}=\dfrac{48}{160}=0,3(mol)$

$\Rightarrow n_{C_2H_2}=\dfrac{n_{Br_2}}{2}=0,15(mol)$

$\Rightarrow V_{C_2H_2}=0,15.22,4=3,36(l)$

$\Rightarrow V_{CH_4}=5,6-3,36=2,24(l)$

Bài 1:

\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,05\left(mol\right)\)

\(\Rightarrow V_{C_2H_4}=0,05.22,4=1,12\left(l\right)\)

\(\Rightarrow V_{CH_4}=3,36-1,12=2,24\left(l\right)\)

Bài 2:

Ta có: \(n_{C_2H_2}+n_{C_2H_4}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(1\right)\)

m _{dd tăng} = m_C2H2 + m_C2H4

\(\Rightarrow6,8=26n_{C_2H_2}+28n_{C_2H_4}\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_2}=0,1\left(mol\right)\\n_{C_2H_4}=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{C_2H_2}=0,1.22,4=2,24\left(l\right)\\V_{C_2H_4}=0,15.22,4=3,36\left(l\right)\end{matrix}\right.\)