Ta có: m₁ = m₂ = 11,05 (g)

Phần 1:

PT: \(2Zn+O_2\underrightarrow{t^o}2ZnO\)

\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

\(2Mg+O_2\underrightarrow{t^o}2MgO\)

Theo ĐLBT KL, có: m_KL + m_O2 = m _oxit

⇒ m_O2 = 18,25 - 11,05 = 7,2 (g)

\(\Rightarrow n_{O_2}=\dfrac{7,2}{32}=0,225\left(mol\right)\)

Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}+\dfrac{3}{4}n_{Al}+\dfrac{1}{2}n_{Mg}=0,225\left(mol\right)\)

\(\Rightarrow n_{Zn}+\dfrac{3}{2}n_{Al}+n_{Mg}=0,45\left(1\right)\)

Phần 2:

PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}+n_{Mg}\left(2\right)\)

Từ (1) và (2) \(\Rightarrow n_{H_2}=0,45\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,45.22,4=10,08\left(l\right)\)

Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,45\left(mol\right)\)

Theo ĐLBT KL, có: m_KL + m_H2SO4 = m _muối + m_H2

⇒ m _{chất rắn khan} = m _muối = 11,05 + 0,45.98 - 0,45.2 = 54,25 (g)

Bạn tham khảo nhé!

Đáp án A

Chọn đáp án B

\(m_X = m_{kim\ loại} + m_{O}\\ \Rightarrow n_O = \dfrac{9,2-7,6}{16} = 0,1(mol)\\ n_{H_2} = \dfrac{0,672}{22,4} = 0,03(mol)\\ 2H^+ + 2e \to H_2\\ 2H^+ + O^{2-} \to H_2O\\ n_{H^+} = 2n_{H_2} + 2n_O = 0,1.2 + 0,03.2=0,26(mol)\\ n_{H_2SO_4} = \dfrac{1}{2}n_{H^+} = 0,13(mol)\\ \Rightarrow V = \dfrac{0,13}{0,5} = 0,26(lít)\)

Đáp án C

Cr₂O₃ + 2Al → t 0  Al₂O₃ + 2Cr

Ÿ Phần 2: + NaOH đặc nóng →  0,075 mol H₂

Ÿ Phần 1: + HCl loãng, nóng → 0,15 mol H₂

_{Có  0 , 1 1 < 0 , 25 2} => tính hiệu suất theo lượng Cr₂O₃ phản ứng.

a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau

=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)

Gọi số mol Al, Zn là a, b (mol)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

             a----->1,5a------->0,5a----->1,5a

            Zn + H₂SO₄ --> ZnSO₄ + H₂

             b----->b--------->b----->b

=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)

=> 171a = 161b 

=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)

Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)

b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)

(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)

=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)

\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)

=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)

=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)

a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau

=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)

Gọi số mol Al, Zn là a, b (mol)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

             a----->1,5a------->0,5a----->1,5a

            Zn + H₂SO₄ --> ZnSO₄ + H₂

             b----->b--------->b----->b

=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)

=> 171a = 161b 

=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)

Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)

b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)

(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)

=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)

\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)

=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)

=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)

Chọn đáp án D