PTHH : \(Zn+CuSO_4\rightarrow ZnSO_4+Cu_{\downarrow}\)

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2`

`0,1`    `0,2`            `0,1`        `0,1`             `(mol)`

`n_[HCl]=0,2.1=0,2(mol)`

 `=>m_[Zn]=0,1.65=6,5(g)`

`b)m_[dd HCl]=1,1.200=220(g)`

`=>C%_[ZnCl_2]=[0,1.136]/[6,5+220-0,1.2].100~~6%`

\(a,n_{HCl}=0,2.1=0,2\left(mol\right)\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

            0,1<--0,2------>0,1------->0,1

\(\rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)

\(b,m_{ddHCl}=200.1,1=220\left(g\right)\)

\(\rightarrow m_{dd}=220+6,5-0,1.2=226,3\left(g\right)\\ \rightarrow C\%_{ZnCl_2}=\dfrac{0,1.136}{226,3}.100\%=6\%\)

\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right);n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{ZnCl_2}=136.0,2=27,2\left(g\right);C_{MddHCl}=\dfrac{0,4}{0,1}=4\left(M\right)\\ b,Zn+CuSO_4\rightarrow ZnSO_4+Cu\\ n_{CuSO_4}=\dfrac{20.10\%}{160}=0,0125\left(mol\right);n_{Zn}=0,2\left(mol\right)\\ Vì:\dfrac{0,0125}{1}< \dfrac{0,2}{1}\Rightarrow Zn.dư\\ n_{Zn\left(p.ứ\right)}=n_{ZnSO_4}=n_{CuSO_4}=0,0125\left(mol\right)\\m_{Zn\left(p.ứ\right)}=0,0125.65=0,8125\left(g\right)\\ m_{ddsau}=m_{Zn\left(p.ứ\right)}+m_{ddCuSO_4}=0,8125+20=20,8125\left(g\right)\\ C\%_{ddZnSO_4}=\dfrac{0,0125.161}{20,8125}.100\approx9,67\%\)

Ta có: \(n_{ZnO}=\dfrac{16,2}{81}=0,2\left(mol\right)\)

a, PT: \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

______0,2_____0,4____0,2 (mol)

b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{14,6}{10\%}=146\left(g\right)\)

c, \(C\%_{ZnCl_2}=\dfrac{0,2.136}{16,2+146}.100\%\approx16,77\%\)

Bạn tham khảo nhé!

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)

\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(1........2\)

\(0.1......0.4\)

\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)

\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)

\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)

\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)

\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)

\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)

\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(0.2......0.4..........0.2........0.2\)

\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)

\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)

\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)

\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)

\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)

\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)

2NaOH + CuSO4 → Cu(OH)2 + Na2SO4

n NaOH = 0,2.5 = 1(mol)

n CuSO4 = 0,1.2 = 0,2(mol)

Ta có :

n NaOH / 2 = 0,5 > n CuSO4 / 1 = 0,2 => NaOH dư

n Cu(OH)2 = n CuSO4 = 0,2 mol

=> m A = 0,2.98 = 19,6 gam

n Na2SO4 = n CuSO4 = 0,2 mol

n NaOH pư = 2n CuSO4 = 0,4(mol)

V dd = 0,2 + 0,1 = 0,3(lít)

Suy ra:

CM Na2SO4 = 0,2/0,3 = 0,67M

CM NaOH = (1 - 0,4)/0,3 = 2M

Gọi x, y lần lượt là số mol của Zn và Fe

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

a. PTHH:

Zn + 2HCl ---> ZnCl₂ + H₂ (1)

Fe + 2HCl ---> FeCl₂ + H₂ (2)

Theo PT₍₁₎: \(n_{H_2}=n_{Zn}=x\left(mol\right)\)

Theo PT₍₂₎: \(n_{H_2}=n_{Fe}=y\left(mol\right)\)

=> x + y = 0,3 (*)

Theo đề, ta có: 65x + 56y = 17,7 (**)

Từ (*) và (**), ta có HPT:

\(\left\{{}\begin{matrix}x+y=0,3\\65x+56y=17,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)

=> \(\%_{m_{Zn}}=\dfrac{6,5}{17,7}.100\%=36,72\%\)

\(\%_{m_{Fe}}=100\%-36,72\%=63,28\%\)

b. Ta có: \(n_{hh_{Zn,Fe}}=0,1+0,2=0,3\left(mol\right)\)

Theo PT_{(1, 2)}: \(n_{HCl}=2.n_{hh}=2.0,3=0,6\left(mol\right)\)

=> \(m_{HCl}=0,6.36,5=21,9\left(g\right)\)

=> \(C_{\%_{HCl}}=\dfrac{21,9}{200}.100\%=10,95\%\)