Đặt a, b, c là số mol Mg, Al, Fe

-> mA = 24a + 27b + 56c = 4,3

Với NaOH =>; nH2 = 1,5b = 0,075

Với HCl =>; nH2 = a + 1,5b + c = 0,135

=>a = 0,01; b = 0,05; c = 0,05

=> A gồm Mg (5,47%), Al (30,75%) và Fe (63,78%)

Al(OH)3 tan trong NaOH dư nên chất rắn còn lại gồm MgO (a) và Fe2O3 (0,5c)

=> m rắn = 4,4 gam

Dễ thấy b = c = 5a nên trong x gam A chứa Mg (y), Al (5y) và Fe (5y)

Bảo toàn electron: 2y + 3.5y + 2.5y = 0,6.3

=>y = 1/15

=>x = 439/15 gam

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+3H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=11\\1,5a+b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ a,n_{HCl}=2.n_{H_2}=2.0,4=0,8\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,8}{8}=0,1\left(l\right)\\ b,FeCl_2+2AgNO_3\rightarrow Fe\left(NO_3\right)_2+2AgCl\downarrow\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\downarrow\\ n_{AgCl}=n_{AgNO_3}=3.n_{AlCl_3}+2.n_{FeCl_2}=3.a+2.b=3.0,2+2.0,1=0,8\left(mol\right)\\ \Rightarrow a=\dfrac{170.0,8}{250}.100=54,4\%\\ b=m_{\downarrow}=m_{AgCl}=0,8.143,5=114,8\left(g\right)\)

Mg + 2HCl -> MgCl2 + H2

0.2     0.4         0.2        0.2

\(nHCl=0.2\times2=0.4mol\)

a.\(m=0.2\times24=4.8g\); \(V=0.2\times22.4=4.48l\)

b.MgCl2 + 2NaOH -> Mg(OH)2 + NaCl 

    0.2                              0.2

\(mNaOH=20\%\times100=20g\Rightarrow nNaOH=0.5mol\)

=> MgCl2 hết, NaOH dư

\(mMg\left(OH\right)2=0.2\times58=11.6g\)

a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(FeO+2HCl\rightarrow FeCl_2+H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)

⇒ m_FeO = 12,6 - 5,4 = 7,2 (g)

c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?

d, Cho hh vào dd H₂SO₄ đặc nguội thì có khí thoát ra.

PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)

Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)

Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)

\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)

- Thấy Cu không phản ứng với HCl .

\(\Rightarrow m_{cr}=m_{Cu}=6,4\left(g\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

.x.......................................1,5x.........

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

.y....................................y.............

Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}27x+56y+6,4=17,4\\1,5x+y=0,4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\) ( mol )

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=5,4\\m_{Fe}=5,6\end{matrix}\right.\) ( g )

b, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)

.......0,1.........0,2...............................

\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)

...0,2.......0,6..........................

\(\Rightarrow n_{NaOH}=0,2+0,6=0,8< 1\)

=> Trong B còn có HCl dư .

\(NaOH+HCl\rightarrow NaCl+H_2O\)

...0,2..........0,2....................

=> Dư 0,2 mol HCl .

\(\Rightarrow n_{HCl}=2n_{H_2}+0,2=1\left(mol\right)\)

\(\Rightarrow m_{ddB}=17,4+250-6,4-0,8=260,2\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{260,2}.100\%\approx2,8\%\\C\%_{FeCl_2}\approx4,88\%\\C\%_{AlCl_3}\approx10,26\%\end{matrix}\right.\)

Vậy ....

\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)

\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)

\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)

0,02                                                   0,06

\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)

0,05                          0,05

\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)