a)

Gọi $n_{Zn} = a(mol) ; n_{Al} = b(mol) \Rightarrow 65a + 27b = 11,9(1)$

$Zn + 2HCl \to ZnCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : 

$n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$

Từ (1)(2) suy ra : a = 0,1; b = 0,2

$m_{Zn} = 0,1.65 = 6,5(gam)$

$m_{Al} = 0,2.27 = 5,4(gam)$

b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$C\%_{HCl} = \dfrac{0,8.36,5}{125}.100\% = 23,36\%$

Em đăng sang môn Hoá nha

\(2Al+6HCl->2AlCl_3+3H_2\\ Fe+2HCl->FeCl_2+H_2\\ n_{Al}=a;n_{Fe}=b\\ 27a+56b=8,3\\ 1,5a+b=\dfrac{5,6}{22,4}=0,25\\ a=b=0,1\\ m_{Al}=27\cdot0,1=2,7g\\ m_{Fe}=8,3-2,7=5,6g\\ a=\dfrac{3a+2b}{500}\cdot36,5=3,65\%\\ m_{ddsau}=508,3-0,25\cdot2=507,8g\\ C\%_{AlCl_3}=\dfrac{133,5a}{507,8}=2,63\%\\ C\%_{FeCl_2}=\dfrac{127b}{507,8}=2,50\%\)

\(n_{HCl}=2.0,4=0,8(mol)\\ n_{Fe}=x(mol);n_{Al}=y(mol)\\ \Rightarrow 56x+27y=11(1)\\ Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow 2x+3y=0,8(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\)

\(a,\Sigma n_{H_2}=x+1,5y=0,4(mol)\\ \Rightarrow V_{H_2}=0,4.22,4=8,96(l)\\ b,m_{Fe}=0,1.56=5,6(g);m_{Al}=0,2.27=5,4(g)\\ c,m_{dd_{HCl}}=400.1,12=448(g)\\ n_{FeCl_2}=0,1(mol);n_{AlCl_3}=0,2(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,1.127}{5,6+448-0,1.2}.100\%=2,8\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{5,4+448-0,3.2}.100\%=5,9\%\)

\(a,\) Đặt \(\begin{cases} n_{Fe}=x(mol)\\ n_{Al}=y(mol) \end{cases}\Rightarrow 56x+27y=22(1)\)

\(n_{H_2}=\dfrac{17,92}{22,4}=0,8(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow x+1,5y=0,8(2)\\ (1)(2)\Rightarrow \begin{cases} x=0,2(mol)\\ y=0,4(mol) \end{cases} \Rightarrow \begin{cases} \%_{Fe}=\dfrac{0,2.56}{22}.100\%=50,91\%\\ \%_{Al}=100\%-50,91\%=49,09\% \end{cases} \)

\(b,\Sigma n_{HCl}=2n_{Fe}+3n_{Al}=0,4+1,2=1,6(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{1,6.36,5}{3,7\%}=1578,38\%\)

Gọi số mol Al, Fe là a, b

\(m_{Cu}=m_B=6,4\left(g\right)\)

=> \(m_{Al}+m_{Fe}=17,4-6,4=11\left(g\right)\)

=> 27a + 56b = 11

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂ 

            b----------------------->b

            2Al + 6HCl --> 2AlCl₃ + 3H₂

             a------------------------>1,5a

=> 1,5a + b = 0,4

=> a = 0,2; b = 0,1

=> \(\left\{{}\begin{matrix}m_{Fe}=0,1.56=5,6\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)

a, \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: 2Al + 6HCl → 2AlCl₃ + 3H₂

Mol:      x                                   1,5x

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:     y                                   y

b, Ta có hpt: \(\left\{{}\begin{matrix}27x+56y=11\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\Rightarrow\%m_{Al}=\dfrac{0,2.27.100\%}{11}=49,09\%\Rightarrow\%m_{Fe}=100\%-49,09\%=50,91\%\)

c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

Ta có: \(\dfrac{0,2}{1}< \dfrac{0,4}{1}\) ⇒ CuO hết, H₂ dư

PTHH: CuO + H₂ → Cu + H₂O

Mol:      0,2                0,2

\(m_{Cu}=0,2.64=12,8\left(g\right)\)

Gọi \(m_{Al}=a\left(g\right)\left(0< a< 11\right)\)

\(\rightarrow m_{Fe}=11-a\left(g\right)\)

\(\rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{a}{27}\left(mol\right)\\n_{Fe}=\dfrac{11-a}{56}\left(mol\right)\end{matrix}\right.\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\dfrac{a}{27}\)                                       \(\dfrac{a}{18}\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(\dfrac{11-a}{56}\)                             \(\dfrac{11-a}{56}\)

\(\rightarrow pt:\dfrac{a}{18}+\dfrac{11-a}{56}=0,4\\ \Leftrightarrow m_{Al}=a=5,4\left(g\right)\left(TM\right)\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{5,4}{11}=49,1\%\\\%m_{Fe}=100\%-49,1\%=50,9\%\end{matrix}\right.\)

\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PTHH: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

LTL: \(0,2< 0,4\rightarrow\) H₂ dư

\(n_{Cu}=n_{CuO}=0,2\left(mol\right)\rightarrow m_{CuO}=0,2.64=12,8\left(g\right)\)

a. \(n_{H_2}=\dfrac{8.96}{22,4}=0,4\left(mol\right)\)

PTHH : 2Al + 6HCl -> 2AlCl₃ + 3H₂

              \(\dfrac{0.8}{3}\)                             0,4

             Fe + 2HCl -> FeCl₂ + H₂

\(m_{Al}=\dfrac{0,8.27}{3}=7,2\left(g\right)\)

\(m_{Fe}=11-7,2=3,8\left(g\right)\)

b. \(\%m_{Al}=\dfrac{7.2}{11}.100=65,5\%\)

\(\%m_{Fe}=100\%-65,5\%=34,5\%\)

c. \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PTHH : H₂ + CuO ----t^o----> Cu + H₂O

                      0,2                  0,2

\(m_{Cu}=0,2.64=12,8\left(g\right)\)

a, Ta có: 24n_Mg + 56n_Fe = 12,8 (1)

PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo PT: \(n_{H_2}=n_{Mg}+n_{Fe}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,3\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,3.24=7,2\left(g\right)\\m_{Fe}=0,1.56=5,6\left(g\right)\end{matrix}\right.\)

b, \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)

\(\Rightarrow V_{HCl}=\dfrac{0,8}{2}=0,4\left(l\right)\)

c, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)

\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)

Theo PT: \(\left\{{}\begin{matrix}n_{Mg\left(OH\right)_2}=n_{MgCl_2}=n_{Mg}=0,3\left(mol\right)\\n_{Fe\left(OH\right)_2}=n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{\downarrow}=0,3.58+0,1.90=26,4\left(g\right)\)

a. Số gam mỗi kim loại trong hỗn hợp ban đầu:

b. Thể tích dung dịch HCl 2M đã phản ứng: 0,2 lít

c. Khối lượng kết tủa thu được khi dd A tác dụng với dung dịch NaOH dư là 0,4 gam.

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