Chọn đáp án A

Câu này rất đơn giản dữ kiện 0,54 gam Al không cần thiết.Kết tủa lớn nhất khi Na trong NaOH chạy vào NaCl và Na₂SO₄

Ta có

\(a.m_{ddNaCl}=\dfrac{15}{5}\cdot100=300g\\ b.m_{nước}+m_{muối}=m_{dd,muối}\\ \Rightarrow m_{nước}=m_{dd,muối}-m_{muối}\\ =300-15\\ =285g\)

1. \(n_{H_2SO_4\left(98\%\right)}=\dfrac{30.1,84.98\%}{98}=0,552\left(mol\right)\)

=>\(V_{H_2SO_4\left(1M\right)}=\dfrac{0,552}{1}=0,552\left(l\right)\)

\(n_{Na}=\dfrac{2.3}{23}=0.1\left(mol\right)\)

\(n_{HCl}=0.4\cdot2=0.8\left(mol\right)\)

\(NaOH+HCl\rightarrow NaCl+H_2O\)

\(0.8..............0.8\)

\(2Na+2H_2O\rightarrow2NaOH+H_{_{ }2}\)

\(0.1........................0.1\)

\(n_{NaOH}=0.1< 0.8\)

Đề nhầm lãn !

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 PTHH: \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)  (1)

             \(HCl+NaOH\rightarrow NaCl+H_2O\)  (2)

             \(AlCl_3+3NaOH\rightarrow3NaCl+Al\left(OH\right)_3\downarrow\)  (3) 

Ta có: \(\left\{{}\begin{matrix}n_{Al_2O_3}=\dfrac{6,12}{102}=0,06\left(mol\right)\\\Sigma n_{HCl}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,06}{1}< \dfrac{0,4}{6}\) \(\Rightarrow\) HCl còn dư, Al₂O₃ p/ứ hết 

Vì bazơ mạnh sẽ p/ứ với axit mạnh trước nên sẽ xảy ra p/ứ (2) và (3)

Lại có: \(n_{Al\left(OH\right)_3}=\dfrac{7,8}{78}=0,1\left(mol\right)=n_{AlCl_3\left(3\right)}\)

Theo PTHH (1): \(n_{AlCl_3\left(1\right)}=0,12\left(mol\right)\)

\(\Rightarrow\) AlCl₃ còn dư nên tính theo Al(OH)₃ \(\Rightarrow n_{NaOH\left(3\right)}=0,3\left(mol\right)\)

Mặt khác: \(n_{HCl\left(dư\right)}=n_{HCl\left(2\right)}=0,04\left(mol\right)=n_{NaOH\left(2\right)}\)

\(\Rightarrow\Sigma n_{NaOH}=0,34\left(mol\right)\) \(\Rightarrow V_{NaOH}=\dfrac{0,34}{2}=0,17\left(l\right)=170\left(ml\right)\) 

Mình đéo giúp

Câu 1:

PT ion: \(H^++OH^-\rightarrow H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{OH^-}=0,6\cdot0,4+0,6\cdot0,3\cdot2=0,6\left(mol\right)\\n_{H^+}=0,2\cdot2,6=0,52\left(mol\right)\end{matrix}\right.\) 

\(\Rightarrow\) H⁺ hết, OH^- còn dư \(\Rightarrow n_{OH^-\left(dư\right)}=0,08\left(mol\right)\)

\(\Rightarrow\left[OH^-\right]=\dfrac{0,08}{0,6+0,2}=0,1\left(M\right)\) \(\Rightarrow pH=14+log\left(0,1\right)=13\)

Bài 2:

PT ion: \(H^++OH^-\rightarrow H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{OH^-}=0,3\cdot1,6=0,48\left(mol\right)\\n_{H^+}=0,2\cdot1\cdot2+0,2\cdot2=0,8\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\) OH^- hết, H⁺ còn dư \(\Rightarrow n_{H^+\left(dư\right)}=0,32\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,32}{0,2+0,3}=0,64\left(M\right)\) \(\Rightarrow pH=-log\left(0,64\right)\approx0,19\)

\(m_{NaOH\left(35\%\right)}=100.35\%=35\left(g\right)\)

\(m_{ddNaOH\left(20\%\right)}=\dfrac{35}{20}.100=175\left(g\right)\)

⇒ m_{nước thêm vào} = 175-100 = 75(g)

_{Vnước thêm vào} = 75.1 = 75 (ml)

Câu 4:

\(n_{HCl}=4.2,75=11\left(mol\right)\)

Ta có: \(V_{ddHCl\left(2M\right)}=\dfrac{n_{HCl\left(1\right)}}{2}\left(l\right);V_{ddHCl\left(3M\right)}=\dfrac{n_{HCl\left(2\right)}}{3}\left(l\right)\)

  \(\Rightarrow V_{ddHCl\left(2M\right)}+V_{ddHCl\left(3M\right)}=\dfrac{n_{HCl\left(1\right)}}{2}+\dfrac{n_{HCl\left(2\right)}}{3}\)

  \(\Leftrightarrow4=\dfrac{3n_{HCl\left(1\right)}+2n_{HCl\left(2\right)}}{6}\Leftrightarrow3n_{HCl\left(1\right)}+2n_{HCl\left(2\right)}=24\)

Ta có: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}+n_{HCl\left(2\right)}=11\\3n_{HCl\left(1\right)}+2n_{HCl\left(2\right)}=24\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2\\n_{HCl\left(2\right)}=9\end{matrix}\right.\)

  \(\Rightarrow V_{ddHCl\left(2M\right)}=\dfrac{2}{2}=1\left(l\right);V_{ddHCl\left(3M\right)}=\dfrac{9}{3}=3\left(l\right)\)

Câu 3:

\(m_{NaOH}=35.100\%=35\left(g\right)\\ m_{H_2O\left(thêm\right)}=a\left(g\right)\\ \Rightarrow\dfrac{35}{100+a}.100\%=20\%\\ \Leftrightarrow a=75\left(g\right)\\ \Rightarrow V_{H_2O\left(thêm\right)}=\dfrac{75}{1}=75\left(ml\right)\)

Câu 4:

\(Đặt:V_{ddHCl\left(pha.thêm2M\right)}=a\left(l\right)\\ V_{ddHCl\left(pha.thêm3M\right)}=b\left(l\right)\\ \Rightarrow\dfrac{2a+3b}{a+b}=2,75\left(1\right)\\ Mà:a+b=4\left(2\right)\\ Từ\left(1\right),\left(2\right)\Rightarrow\left\{{}\begin{matrix}a=1\left(l\right)\\b=3\left(l\right)\end{matrix}\right.\)

Vậy cần pha 1 lít dung dịch HCl 2M vào 3 lít dung dịch HCl 3M để thu được 4 lít dung dịch HCl 2,75M 

Chúc em học tốt!

\(a,m_{NaCl}=\dfrac{8.200}{100}=16\left(g\right)\\ b,m_{HCl}=\dfrac{250.14}{100}=35\left(g\right)\\ m_{H_2SO_4}=\dfrac{19,6.300}{100}=58,8\left(g\right)\)

\(n_{H_2SO_4}=\dfrac{19,6\%.500.1,12}{98}=1,12\left(mol\right)\\n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ MgO+H_2SO_4 \rightarrow MgSO_4+H_2O\\ CaCO_3+H_2SO_4\rightarrow CaSO_4+CO_2+H_2O\\ TH1:axit.hết\\ n_{CO_2}=n_{CaCO_3}=0,1\left(mol\right)\\ \Rightarrow n_{MgO}=\dfrac{18-0,1.10}{40}=0,2\left(mol\right)\\ n_{H_2SO_4\left(p.ứ\right)}=0,2+0,1=0,3\left(mol\right)< 1,12\left(mol\right)\\ \Rightarrow LoạiTH1\\ TH2:axit.dư\\ \Rightarrow\left\{{}\begin{matrix}40a+100b=18\\b=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \Rightarrow\%m_{MgO}=\dfrac{0,2.40}{18}.100\approx44,444\%\Rightarrow\%m_{CaCO_3}\approx55,556\%\)

\(b,m_{ddB}=m_A+m_{ddH_2SO_4}-m_{CO_2}=18+500.1,12-0,1.44=573,6\left(g\right)\\ n_{H_2SO_4\left(dư\right)}=1,12-0,3=0,82\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,82.98}{573,6}.100\approx14,01\%\\ C\%_{ddCaCl_2}=\dfrac{0,1.111}{573,6}.100\approx1,935\%\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{573,6}.100\approx3,312\%\)