- Đặt \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{CH_3COOH}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow46a+60b=33,2\left(1\right)\)

\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

a) \(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)

       2                                      2             1     (mol)

       a                                      a           a/2   (mol)

\(2CH_3COOH+2Na\rightarrow2CH_3COONa+H_2\)

      2                                       2                    1    (mol)

     b                                        b                b/2  (mol)

Từ hai PTHH trên ta có: \(\dfrac{a}{2}+\dfrac{b}{2}=n_{H_2}=0,3\Rightarrow a+b=0,6\left(2\right)\)

(1), (2) ta có hệ phương trình: \(\left\{{}\begin{matrix}46a+60b=33,2\\a+b=0,6\end{matrix}\right.\)

Giải ra ta được: \(a=0,2\left(mol\right);b=0,4\left(mol\right)\)

b) \(m_{C_2H_5OH}=n.M=0,2\times46=9,2\left(g\right)\)

\(m_{CH_3COOH}=n.M=0,4\times60=24\left(g\right)\)

c) \(m_{C_2H_5ONa}=n.M=0,2\times68=13,6\left(g\right)\)

\(m_{CH_3COONa}=n.M=0,4\times82=32,8\left(g\right)\)

+PTHH:

CH3COOH + Na => CH3COONa + 1/2 H2

C2H5OH + Na => C2H5ONa + 1/2 H2

Ta có: nH2 = V/22.4 = 6.72/22.4 = 0.3 (mol)

Gọi x (mol), y(mol) lần lượt là số mol phản ứng của CH3COOH và C2H5OH

Ta có: \(\left\{{}\begin{matrix}60x+46y=33.2\\\frac{1}{2}x+\frac{1}{2}y=0.3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0.4\\y=0.2\end{matrix}\right.\)

mCH3COOH = n.M = 0.4 x 60 = 24 (g)

mC2H5OH = n.M = 0.2 x 46 = 9.2 (g)

+PTHH:

CH3COOH + C2H5OH <=> (H2SO4đ,t^o) CH3COOC2H5 + H2O

Ta có: nCH3COOH = 0.4 (mol)

nC2H5OH = 0.2 (mol)

Lập tỉ số: 0.4/1 > 0.2/1 => CH3COOH dư, C2H5OH hết

Đặt số mol của C2H5OH lên phương trình

===> nCH3COOC2H5 = 0.2 (mol)

mCH3COOC2H5 lý thuyết = n.M = 0.2 x 88 = 17.6 (g)

mCH3COOC2H5 thu được = mCH3COOC2H5 lý thuyết.H(%) = 17.6 x 80/100 = 14.08 (g)

Bài 1

\(a)n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)

0,15      0,3          0,15         0,15

\(\%m_{Fe}=\dfrac{0,15.56}{12}\cdot100\%=70\%\\ \%m_{FeO}=100\%-70\%=30\%\\ b)n_{FeO}=\dfrac{12-0,15.56}{72}=0,05mol\\ FeO+2HCl\rightarrow FeCl_2+H_2O\)

0,05        0,1

\(V_{ddHCl}=\dfrac{0,1+0,3}{2}=0,2l\)

Bài 2

\(a)Na_2O+H_2O\rightarrow2NaOH\\ b)BaO+H_2O\rightarrow Ba\left(OH\right)_2\\ c)BaSO_4?\\ BaO+H_2O\rightarrow Ba\left(OH\right)_2\\ Ba\left(OH\right)_2+CuSO_4\rightarrow BaSO_4+Cu\left(OH\right)_2\\ d)Na_2O+H_2O\rightarrow2NaOH\\ 2NaOH+CuSO_4\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\ e)Na_2O+H_2O\rightarrow2NaOH\\ 2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(CH_3COOH+Na\rightarrow CH_3COONa+\dfrac{1}{2}H_2\)

 0,1                                0,1

\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)

0,1                           0,1

Theo pthh có: \(n_A=2nH_2=2.0,1=0,2\left(mol\right)\)

Gọi x, y là số mol của rượu và axit có trong hh A.

có hệ: \(\left\{{}\begin{matrix}x+y=0,2\\60x+46y=10,6\end{matrix}\right.\)

=> x = y = 0,1

=> \(\left\{{}\begin{matrix}\%_{m_{CH_3COOH}}=\dfrac{60.0,1.100}{10,6}=56,6\%\\\%_{m_{C_2H_5OH}}=100-56,6=43,4\%\end{matrix}\right.\)

\(m_{muối}=m_{CH_3COONa}+m_{C_2H_5ONa}=82.0,1+68.0,1=15\left(g\right)\)

Ta có: \(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)

PT: \(2Na+Cl_2\rightarrow2NaCl\)

____0,1___0,05____0,1 (mol)

a, m_Na = 0,1.23 = 2,3 (g)

b, V_Cl2 = 0,05.22,4 = 1,12 (l)

Bạn tham khảo nhé!

nO2 = 3,36 : 22,4 = 0,15 (mol) 
pthh : 2Mg + O2 -t--> 2MgO
         0,3<----0,15---> 0,3 (mol) 
=> mMg= 0,3 . 24 = 7,2 (g) 
=> mMgO = 0,3 . 40 =12 (g) 
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2 
           0,3<-------------------------------------0,15 (mol) 
=> mKMnO4 = 0,3 . 158 = 47,4 (g) 

a, Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{CH_3COOH}=b\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH: 

2C₂H₅OH + 2Na ---> 2C₂H₅ONa + H₂

a---------------------------------------->0,5a

2CH₃COOH + 2Na ---> 2CH₃COONa + H₂

b------------------------------------------------>0,5b

=> hệ pt \(\left\{{}\begin{matrix}46a+60b=48,8\\0,5a+0,5b=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,8\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_5OH}=0,8.46=36,8\left(g\right)\\m_{CH_3COOH}=0,2.60=12\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100\%=75,41\%\\\%m_{CH_3COOH}=100\%-75,41\%=24,59\%\end{matrix}\right.\)

b, PTHH:

\(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_4đặc}CH_3COOC_2H_5+H_2O\)

LTL: 0,8 > 0,2 => Rượu dư

\(n_{CH_3COOC_2H_5\left(tt\right)}=0,2.85\%=0,17\left(mol\right)\\ m_{este}=0,17.88=14,96\left(g\right)\)

a.Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=x\\n_{CH_3COOH}=y\end{matrix}\right.\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)

\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)

             x                                          1/2 x         ( mol )

\(2CH_3COOH+Na\rightarrow2CH_3COONa+H_2\)

        y                                                      1/2 y       ( mol )

Ta có:

\(\left\{{}\begin{matrix}46x+60y=48,8\\\dfrac{1}{2}x+\dfrac{1}{2}y=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,2\end{matrix}\right.\)

\(\rightarrow m_{C_2H_5OH}=0,8.46=36,8g\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100=75,4\%\\\%m_{CH_3COOH}=100\%-75,4\%=24,6\%\end{matrix}\right.\)

b.\(C_2H_5OH+CH_3COOH\rightarrow\left(H_2SO_4\left(đ\right),t^o\right)CH_3COOC_2H_5+H_2O\)

        0,8     <          0,2                                                                       ( mol )

                               0,2                                             0,2                    ( mol )

\(m_{CH_3COOC_2H_5}=0,2.88.85\%=14,96g\)