\(m_{CH_3COOH}=6\%.200=12\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\uparrow\)

LTL: \(\dfrac{0,2}{2}>0,2\rightarrow\) Zn dư

Theo pthh: \(n_{\left(CH_3COO\right)_2Zn}=n_{Zn\left(pư\right)}=n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\)

\(\rightarrow\left\{{}\begin{matrix}m_{H_2}=0,1.2=0,2\left(g\right)\\m_{Zn\left(pư\right)}=0,1.65=6,5\left(g\right)\\m_{\left(CH_3COO\right)_2Zn}=0,1.183=18,3\left(g\right)\end{matrix}\right.\)

\(\rightarrow m_{dd}=200+6,5-0,2=206,3\left(g\right)\\ \rightarrow C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{18,3}{206,3}=8,87\%\)

a)

$Mg + H_2SO_4 \to MgSO_4 + H-2$

b) $n_{H_2SO_4} = n_{Mg} = \dfrac{4,8}{24} = 0,2(mol)$
$C\%_{H_2SO_4} = \dfrac{0,2.98}{200}.100\% = 9,8\%$

$n_{H_2} = n_{Mg} = 0,2(mol)$

$\Rightarrow m_{dd\ A} = 4,8 + 200 - 0,2.2 = 204,4(gam)$
$C\%_{MgSO_4} = \dfrac{0,2.120}{204,4}.100\% = 11,7\%$

c) $V_{H_2} = 0,2.22,4 = 4,48(lít)$

n_CaCO3=8,4:(40+12+16.3)=0,084 mol

n_H2SO4= 0,5.1=0,5 mol

PTHH:    H2SO4+ CaCO3 --> CaSO4↓ + CO2 +H2O

theo đề:  0,5 mol:    0,084 mol

=> H₂SO₄ de theo CaCO₃

phản ứng :  0,084mol<----0,084 mol---> 0,084mol

=> C_M=\(\frac{0,084}{0,5}=0,168M\)

nNa2CO3 = 10,6 / 106 = 0,1 (mol)

Na2CO3 + 2CH3COOH -> 2CH3COONa + H2O + CO2

0,1               0,2                          0,2                           0,1

mdd CH3COOH = 0,2 * 60 / 5 * 100 = 240 (gam)

CO2 + Ca(OH)2 -> CaCO3 + H2O

0,1                            0,1

mCaCO3 = 0,1 * 100 = 10 (gam)

mdd = 240 + 10,6 - 0,1 * 44 = 246,2 (gam)

C% = 82 * 0,2 / 246,2 * 100% = 6,66%

a.\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1mol\)

\(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2+H_2O\)

    0,1                 0,2                       0,2                 0,1                ( mol )

\(m_{ddCH_3COOH}=\dfrac{0,2.60}{5\%}=240g\)

b.\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

                      0,1          0,1                 ( mol )

\(m_{CaCO_3}=0,1.100=10g\)

c.\(m_{ddspư}=10,6+240-0,1.44=246,2g\)

\(m_{CH_3COONa}=0,2.82=16,4g\)

\(C\%_{CH_3COONa}=\dfrac{16,4}{246,2}.100=6,66\%\)

\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)

PTHH: 

Na₂CO₃ + 2CH₃COOH ---> 2CH₃COONa + CO₂ + H₂O

0,1---------->0,2----------------->0,2--------------->0,1

CO₂ + Ca(OH)₂ ---> CaCO₃ + H₂O

0,1------------------------->0,1

=> \(\left\{{}\begin{matrix}m_{ddCH_3COOH}=\dfrac{0,2.60}{5\%}=240\left(g\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\end{matrix}\right.\)

\(m_{dd}=10,6+240-0,1.44=246,2\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{82.0,2}{246,2}.100\%=6,66\%\)

\(n_{HCl}=\dfrac{44,8}{22,4}=2\)

\(\Rightarrow m_{HCl}=2.36,5=73g\)

=> \(C\%_{HCl}=\dfrac{73}{73+327}\times100\%=18,25\%\)

b. 

\(n_{HCl}=\dfrac{250.18,25\%}{36,5}=1,25mol\)

\(n_{CaCO_3}=\dfrac{50}{100}=0,5mol\)

\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)

\(n_{CaCl_2}=n_{CO_2}=0,5mol\)

\(n_{HClpu}=0,5.2=1mol\)

\(\Rightarrow n_{HCldu}=1,25-1=0,25\)

\(\Rightarrow m_{ddpu}=50+250-0,5.44=278g\)

\(C\%_{HCl}=\dfrac{0,25.36,5}{278}.100\%=3,28\%\)

\(C\%_{CaCl_2}=\dfrac{0,5.111}{278}.100\%=19,96\%\)

HCl k có phần trăm à

\(m_{NaOH\left(A\right)}=20.5\%=1\left(g\right)\)

Trong B:  

gọi x là khối lượng Na2O thêm vào , x>0 (g)

\(10\%=\dfrac{\dfrac{80}{62}x+1}{x+20}\)

\(\rightarrow x=0,84\left(g\right)\)

Vậy khối Na2O thêm vào dd A là 0,84 (g) 

b, \(m_{KOH\left(A\right)}=2\%.20=0,4\left(g\right)\)

\(C\%_{KOH\left(B\right)}=\dfrac{0,4}{20+0,84}.100\%=1,92\%\)

\(n_K=\dfrac{5,85}{39}=0,15\left(mol\right)\)

PTHH: 2K + 2H₂O --> 2KOH + H₂

_____0,15------------->0,15-->0,075

=> V_H2 = 0,075.22,4  =1,68(l)

mdd = 5,85 + 100 - 0,075.2 = 105,7(g)

=> \(C\%=\dfrac{0,15.56}{105,7}.100\%=7,95\%\)

Nồng độ axit là : 1.056%. 

Có nghĩa trong dung dịch có H₂SO₄ dư em nhé. Em cần lời giải không nhỉ ?