a) Gọi số mol Mg, Fe là a, b (mol)

=> 24a + 56b = 11,84

\(n_{HCl}=\dfrac{146.14\%}{36,5}=0,56\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

            a--->2a--------->a----->a

           Fe + 2HCl --> FeCl₂ + H₂

            b-->2b-------->b------>b

=> 2a + 2b = 0,56

=> a = 0,12; b = 0,16

=> \(\left\{{}\begin{matrix}\%Mg=\dfrac{0,12.24}{11,84}.100\%=24,324\%\\\%Fe=\dfrac{0,16.56}{11,84}.100\%=75,676\%\end{matrix}\right.\)

b) \(n_{H_2}=a+b=0,28\left(mol\right)\)

=> \(V_{H_2}=0,28.22,4=6,272\left(l\right)\)

c) m_{dd sau pư} = 11,84 + 146 - 0,28.2 = 157,28 (g)

=> \(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,12.95}{157,28}.100\%=7,25\%\\C\%_{FeCl_2}=\dfrac{0,16.127}{157,28}.100\%=12,92\%\end{matrix}\right.\)

Bài 5:

mCu= 43,24% . 14,8\(\approx\) 6,4(g)

=>mFe\(\approx\) 14,8 - 6,4= 8,4(g)

=> nFe\(\approx\) 8,4/56\(\approx\) 0,15(mol)

PTHH: Fe + 2 HCl -> FeCl2 + H2

nH2=nFe \(\approx\) 0,15 (mol)

=> V(H2,đktc) \(\approx\) 0,15 . 22,4\(\approx\) 3,36(l)

Bài 6:

nH2= 4,368/22,4=0,195(mol)

Đặt: nMg=a(mol); nAl=b(mol) (a,b>0)

PTHH: Mg + 2 HCl -> MgCl2 + H2

a________2a_____a_____a(mol)

2 Al + 6 HCl -> 2 AlCl3 +3 H2

b____3b____b______1,5b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24a+27b=3,87\\a+1,5b=0,195\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,06\\b=0,09\end{matrix}\right.\)

a) nH2SO4= 2a+3b=0,39(mol)

=> mH2SO4= 0,39.98=38,22(g)

b) m(muối)= mMgSO4 + mAl2(SO4)3= 120a+ 133,5b= 120.0,06+133,5.0,09= 19,215(g)

\(n_{H^+}=0,5.0,8+0,25.0,8.2=0,8\left(mol\right)\\ \Rightarrow n_{H_2}=\dfrac{n_{H^+}}{2}=\dfrac{0,8}{2}=0,4\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\)

Không phải KL hhX cho rồi à ta?

\(a,n_{H_2}=\dfrac{2,576}{22,4}=0,115\left(mol\right)\\ Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}95a+133,5b=10,475\\a+1,5b=0,115\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\\ \%m_{Mg}=\dfrac{0,04.24}{0,04.24+0,05.27}.100\approx41,558\%\Rightarrow\%m_{Al}\approx58,442\%\\ b,n_{HCl}=2.n_{H_2}=2.0,115=0,23\left(mol\right)\\ \Rightarrow x=C\%_{ddHCl}=\dfrac{0,23.36,5}{100}.100=8,395\%\)

Chọn đáp án B.

Gọi số mol Al, Mg là a, b (mol)

\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

            a--------------->a------>1,5a

            Mg + 2HCl --> MgCl₂ + H₂

             b--------------->b---->b

=> \(\left\{{}\begin{matrix}1,5a+b=0,6\\133,5a+95b=55,2\end{matrix}\right.\)

=> a = 0,2 (mol); b = 0,3 (mol)

\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{0,2.27+0,3.24}.100\%=42,857\%\\\%m_{Mg}=\dfrac{0,3.24}{0,2.27+0,3.24}.100\%=57,143\%\end{matrix}\right.\)

\(\left\{{}\begin{matrix}Al\\Mg\end{matrix}\right.+HCl->\left\{{}\begin{matrix}AlCl3\\MgCl2\end{matrix}\right.+H2\)

2Al + 3HCl -> 2AlCl3 + 3H2

0,2      0,3                      0,3

Mg + 2HCl -> MgCl2 + H2

0,3      0,6                     0,3

=> mHCl dùng = 0,9 . 36,5 = 32,85 (g)

=> mH2 = 0,6 . 2 = 1,2 (g)

Bảo toàn khối lượng :

=> mX = 55,2 + 1,2 - 32,85 = 23,55 (g)

Ta có :

\(\left\{{}\begin{matrix}3x+2y=1,2\left(bt-e\right)\\133,5x+95y=55,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,3\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%mAl=\dfrac{0,2.27}{0,2.27+0,3.24}=42,85\%\\\%mMg=100\%-42,85\%=57,15\%\end{matrix}\right.\)

Câu 1: 

\(n_{H_2}=\dfrac{2.91362}{22.4}=0.13mol\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

 a           a                a           a

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

 2b          3b               b                 3b

Ta có: \(\left\{{}\begin{matrix}24a+54b=2.58\\a+3b=0.13\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.04\\b=0.03\end{matrix}\right.\)

\(m_{Mg}=0.04\times24=0.96g\)

\(m_{Al}=0.03\times2\times27=1.62g\)

\(V_{H_2SO_4}=\dfrac{0.04+3\times0.03}{0.5}=0.26l\)

Câu 2:

\(n_{H_2}=\dfrac{3.136}{22.4}=0.14mol\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

a            a              a             a

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b           b                 b         b

Ta có: \(\left\{{}\begin{matrix}24a+56b=4.96\\a+b=0.14\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.09\\b=0.05\end{matrix}\right.\)

\(m_{Mg}=0.09\times24=2.16g\)

\(m_{Fe}=0.05\times56=2.8g\)

\(C\%_{H_2SO_4}=\dfrac{0.14\times98\times100}{200}=6.86\%\)

Câu 3: 

\(n_{H_2}=\dfrac{1.568}{22.4}=0.07mol\)

\(Ba+H_2SO_4\rightarrow BaSO_4+H_2\)

a           a              a             a

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

b          b                 b             b

Ta có: \(\left\{{}\begin{matrix}137a+24b=3.94\\a+b=0.07\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.02\\b=0.05\end{matrix}\right.\)

\(m_{Ba}=0.02\times137=2.74g\)

\(m_{Mg}=0.05\times24=1.2g\)

\(CM_{H_2SO_4}=\dfrac{0.07}{0.1}=0.7M\)

Đáp án B

Chú ý: Có H₂ nên N O 3 -  đã hết; N₂O không tác dụng với O₂.